ON THE PHASE DIAGRAM OF THE SYSTEM HYDROXYPROPYLCELLULOSE-WATER

Fischer H.; Keller A.; Odell JA.; Murray M.

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ON THE PHASE DIAGRAM OF THE SYSTEM HYDROXYPROPYLCELLULOSE-WATER

机译：羟丙基纤维素水相图

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The phase diagram of the system hydroxypropylcellulose (HPC)-H2O has been investigated using differential scanning calorimetry (DSC), X-ray diffraction, optical microscopy and H-1 (NMR) nuclear magnetic resonance spectroscopy. A peritectic line at higher temperatures has been found similar to the lytropic systems described before. This phase transition, from a solution consisting of solvate aggregates and free solvent, into a crystal solvate-isotropic phase system is completely reversible. The formation of crystal solvate phases is independent of the water content of the system until the system transforms into a thermotropic system. The solvent molecules are strongly associated with the macromolecules. [References: 12]

机译：使用差示扫描量热法（DSC），X射线衍射，光学显微镜和H-1（NMR）核磁共振波谱研究了系统羟丙基纤维素（HPC）-H2O的相图。已经发现高温下的包晶线类似于前述的溶致体系。从溶剂化物聚集体和游离溶剂组成的溶液到结晶溶剂化物各向同性相系统的这种相变是完全可逆的。晶体溶剂化物相的形成与系统的水含量无关，直到系统转变为热致体系。溶剂分子与大分子紧密结合。 [参考：12]

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《Journal of Materials Science》 |1995年第18期|共5页
作者
Fischer H.; Keller A.; Odell JA.; Murray M.;
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正文语种 eng
中图分类工程材料学;
关键词
Aqueous-solutions; (hydroxypropyl)cellulose; Cellulose;

机译：水溶液;（羟丙基）纤维素;纤维素;

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专利

1. ON THE PHASE DIAGRAM OF THE SYSTEM HYDROXYPROPYLCELLULOSE-WATER [J] . Fischer H., Keller A., Odell JA., Journal of Materials Science . 1995,第18期

机译：羟丙基纤维素水相图
2. Liquid-liquid miscibility gaps and hydrate formation in drug-water binary systems: pressure-temperature phase diagram of lidocaine and pressure-temperature-composition phase diagram of the lidocaine-water system. [J] . Ceolin R, Barrio M, Tamarit JL, Journal of pharmaceutical sciences. . 2010,第6期

机译：药物-水二元系统中的液-液混溶间隙和水合物形成：利多卡因的压力-温度相图和利多卡因-水系统的压力-温度-组成相图。
3. The Microemulsion Phase in the System.Phase Diagram Bromide/Dodecane/Water Syatem.Phase Diagram,Microstructure,and Nucleation Kinetics of Exxess Oil Phase [J] . Andreas Arvidsson, Olle Soderman Langmuir: The ACS Journal of Surfaces and Colloids . 2001,第12期

机译：系统中的微乳液相。溴化物/十二烷/水系统的相图。相图，微结构和过量油相的成核动力学
4. Development on Applying Phase Diagram to Evaluation Method of Refractory Layer Erosion for Passive Debris Cooling System: Fundamental Study of UO_2-ZrO_2-Al_2O_2 Phase Diagram [C] . Yuya Takahashi, Tomohisa Kurita, Satoru Kuboya, International congress on advances in nuclear power plants . 2016

机译：相图在被动碎屑冷却系统耐火层侵蚀评价方法中的应用研究：UO_2-ZrO_2-Al_2O_2相图的基础研究
5. Pressure-temperature phase diagram of tris(hydroxymethyl)aminomethane and phase diagram determination of tris(hydroxymethyl)aminomethane -- 2-amino-2-methyl-1, 3-propanediol (AMPL) binary system. [D] . Kamisetty, Vamsi Krishna. 2010

机译：三（羟甲基）氨基甲烷的压力-温度相图和三（羟甲基）氨基甲烷-2-氨基-2-甲基-1,3-丙二醇（AMPL）二元体系的相图测定。
6. Determination of the quaternary phase diagram of the water-ethylene glycol-sucrose-NaCl system and a comparison between two theoretical methods for synthetic phase diagrams [O] . Xu Han, Yang Liu, John K. Critser -1

机译：含水 - 乙二醇 - 蔗糖 - NaCl系统的季图和综合相图的两种理论方法的测定
7. Comment on “Determination of the quaternary phase diagram of the water–ethylene glycol–sucrose–NaCl system and a comparison between two theoretical methods for synthetic phase diagrams” Cryobiology 61 (2010) 52–57 [O] . Zielinski Michal W., McGann Locksley E., Nychka John A., 2015

机译：评论“确定水-乙二醇-蔗糖-NaCl体系的季相图以及两种合成相图的理论方法之间的比较”，《低温生物学》 61（2010）52-57
8. Thermochemical Stability Diagrams for Condensed Phases and Volatility Diagrams for Volatile Species over Condensed Phases in Twenty Metal-Sulfur-Oxygen Systems Between 1150 and 1450 exp 0 K. [R] . Gulbransen, E. A., Meier, G. H. 1980

机译：二十金属 - 硫 - 氧系统中凝聚相的挥发性物质的凝聚相和挥发性图的热化学稳定性图表在1150和1450之间。

ON THE PHASE DIAGRAM OF THE SYSTEM HYDROXYPROPYLCELLULOSE-WATER

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