Studies on the miscibility of poly(2-hydroxyethyl methacrylate) and poly(ethylene oxide) blends

Prashantha K; Pai KVK; Sherigara BS

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Studies on the miscibility of poly(2-hydroxyethyl methacrylate) and poly(ethylene oxide) blends

机译：聚（甲基丙烯酸2-羟乙酯）与聚（环氧乙烷）混合物的混溶性研究

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Miscibility characteristics of poly[2-hydroxyethylmethacrylate] (PHEMA) and poly[ethylene oxide] (PEO) have been investigated by solution viscometry, ultrasonic and differential scanning calorimetric (DSC) methods. The interaction parameters were obtained using the viscosity data. Ultrasonic velocity and adiabatic compressibility vs. blend composition have been plotted and are found to be linear. A single glass transition temperature was observed by differential scanning calorimetry. Variation of glass transition temperature (T-g) with composition follows Garden-Taylor equation. T-g values have also been calculated from the Fox equation. The results obtained reveal that PHEMA forms a miscible blend with PEO in the entire composition range.

机译：通过溶液粘度法，超声波和差示扫描量热法（DSC）研究了聚[甲基丙烯酸2-羟乙酯]（PHEMA）和聚[环氧乙烷]（PEO）的混溶特性。使用粘度数据获得相互作用参数。绘制了超声波速度和绝热压缩率与共混物的关系曲线，发现它们是线性的。通过差示扫描量热法观察到单一的玻璃化转变温度。玻璃化转变温度（T-g）随组成的变化遵循Garden-Taylor方程。 T-g值也已从Fox方程计算得出。获得的结果表明，PHEMA在整个组成范围内与PEO形成可混溶的混合物。

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《Journal of Macromolecular Science. Pure and Applied Chemistry》 |2008年第3期|共4页
作者
Prashantha K; Pai KVK; Sherigara BS;
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正文语种 eng
中图分类高分子化学（高聚物）;
关键词
polymer blends; miscibility; poly2-hydroxyethylmethacrylate; polyethylene oxide; POLYMER-POLYMER MISCIBILITY; 2 INCOMPATIBLE POLYMERS; SOLUTION VISCOMETRY; SOLID-STATE; COMPATIBILIZER; POLYSTYRENE;

机译：聚合物共混物;混溶性;聚[甲基丙烯酸2-羟乙酯];聚[环氧乙烷];聚合物-聚合物混溶性;2种不相容的聚合物;溶液粘度;固态;相容性;聚苯乙烯;

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1. Studies on the miscibility of poly(2-hydroxyethyl methacrylate) and poly(ethylene oxide) blends [J] . Prashantha K, Pai KVK, Sherigara BS Journal of Macromolecular Science. Pure and Applied Chemistry . 2008,第3期

机译：聚（甲基丙烯酸2-羟乙酯）与聚（环氧乙烷）混合物的混溶性研究
2. A solid-state C-13 NMR study on phase heterogeneity in the miscible blend of amorphous poly(benzyl methacrylate) with semicrystalline poly(ethylene oxide) [J] . Lin RH., Chiang JC., Woo EM. Polymer: The International Journal for the Science and Technology of Polymers . 2001,第9期

机译：固态C-13 NMR研究非晶态聚（甲基丙烯酸苄酯）与半结晶聚（环氧乙烷）混溶共混物中的相异质性
3. A solid-state ~13C NMR study on phase heterogeneity in the miscible blend of amorphous poly(benzyl methacrylate) with semicrystalline poly(ethylene oxide) [J] . Rong-Hsien Lin, E.M.Woo, Jin C.Chiang Polymer: The International Journal for the Science and Technology of Polymers . 2001,第9期

机译：固态〜13C NMR研究非晶态聚（甲基丙烯酸苄酯）与半结晶聚（环氧乙烷）混溶共混物中的相异质性
4. Physical and Interaction Characteristic of Polyhedral Oligomeric Silsesquioxane (POSS) Nanohybids with Miscible Polymer Blends of Poly(ethylene oxide) (PEO) and Poly(methyl methacrylate) (PMMA) [C] . Hye-Ri Pyo, Nam-Seok Jo, Na-Youn Kim PMSE Symposia . 2011

机译：聚（氧化乙烷）（PEO）和聚（甲基丙烯酸甲酯）（PMMA）与聚合物混合聚合物共混物（PMMA）的多面体低聚二钠（POSS）纳米骨的物理和相互作用特性
5. Terminal component dynamics in poly(ethylene oxide)/poly(methyl methacrylate) blends. [D] . Zeroni, Ilan. 2008

机译：聚环氧乙烷/聚甲基丙烯酸甲酯共混物中的末端组分动力学。
6. Melt Rheological Behavior and Morphology of Poly(ethylene oxide)/Natural Rubber-graft-Poly(methyl methacrylate) Blends [O] . Nurul Fatahah Asyqin Zainal, Say Aik Lai, Chin Han Chan 2020

机译：聚（环氧乙烷）/天然橡胶接枝-聚（甲基丙烯酸甲酯）共混物的熔体流变行为和形态
7. Poly(ethylene oxide)/ poly(methyl methacrylate) blends: Influence of tacticity of poly(methyl methacrylate) on blend structure and miscibility [O] . MacKnight, William, Silvestre, C., Cimmino, S., 1987

机译：聚（环氧乙烷）/聚（甲基丙烯酸甲酯）共混物：聚（甲基丙烯酸甲酯）的立构规整度对共混物结构和混溶性的影响

Studies on the miscibility of poly(2-hydroxyethyl methacrylate) and poly(ethylene oxide) blends

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