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首页> 外文期刊>Journal of Macromolecular Science. Pure and Applied Chemistry >In situ formation of silver nanoparticles in regenerated cellulose-polyacrylic acid (RC-PAAc) hydrogels for antibacterial application
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In situ formation of silver nanoparticles in regenerated cellulose-polyacrylic acid (RC-PAAc) hydrogels for antibacterial application

机译:用于抗菌应用的再生纤维素-聚丙烯酸(RC-PAAc)水凝胶中原位形成银纳米颗粒

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摘要

In this work, free-radical aqueous polymerization of acrylic acid (AAc) was carried-out in cellulose solution(dissolved in NaOH/urea system) followed by equilibration in ammonium sulfate solution to yield Regenerated Cellulose-Poly-acrylic acid (RC-PAAc) hydrogels.The water absorbency of these gels was investigated as a function of concentration of cellulose, acrylic acid and cross-linker N,Nmethylene bis-acrylamide. A negative concentration dependence of water uptake was observed. The gels were loaded with silver nitrate solution followed by borohydride reduction to yield silver nano particles loaded hydrogels. These gels were characterized by TGA, and TEM analysis. Finally the silver nano particles loaded gels demonstrated fair antibacterial activity against E.coli as model bacteria.
机译:在这项工作中,在纤维素溶液(溶于NaOH /脲系统)中进行丙烯酸(AAc)的自由基水聚合,然后在硫酸铵溶液中进行平衡,以生成再生纤维素-聚丙烯酸(RC-PAAc)。研究了这些凝胶的吸水率与纤维素,丙烯酸和交联剂N,N亚甲基双丙烯酰胺的浓度的关系。观察到水吸收的负浓度依赖性。凝胶中负载有硝酸银溶液,然后硼氢化物还原以产生负载银纳米颗粒的水凝胶。这些凝胶通过TGA和TEM分析表征。最终,载有银纳米颗粒的凝胶显示出对作为模型细菌的大肠杆菌的公平抗菌活性。

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