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首页> 外文期刊>Journal of Materials Chemistry, A. Materials for energy and sustainability >A successive-reaction nanoreactor made of active molecularly imprinted polymer containing Ag nanoparticles
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A successive-reaction nanoreactor made of active molecularly imprinted polymer containing Ag nanoparticles

机译:由含银纳米粒子的活性分子印迹聚合物制成的连续反应纳米反应器

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摘要

A successive-reaction nanoreactor made of a unique molecularly imprinted polymer containing Ag nanoparticles is reported. This molecularly Imprinted polymer was fabricated using two well-coupled templates, i.e., 4-nitrophenyl acetate and 4-nitrophenol, The catalytic hydrolysis of the former by this nanoreactor led to the formation of the latter, which was further reduced by the nanoreactor to 4-aminophenol. Unlike reported nanoreactors, which usually promote one single reaction, this novel nanoreactor can run cascade reactions. The proposed integration of active molecularly imprinted polymers with metal nanoparticles opens a new opportunity for creating functional catalysts for complicated chemical processes.
机译:据报道,由包含银纳米颗粒的独特分子印迹聚合物制成的连续反应纳米反应器。该分子印迹聚合物是使用两个偶联良好的模板(即乙酸4-硝基苯酯和4-硝基苯酚)制造的。前者被该纳米反应器催化水解导致后者形成,而后者被纳米反应器进一步还原为4 -氨基苯酚。与报道的通常会促进一个单一反应的纳米反应器不同,这种新型纳米反应器可以进行级联反应。活性分子印迹聚合物与金属纳米颗粒的拟议集成为为复杂化学过程制备功能性催化剂开辟了新机会。

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