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首页> 外文期刊>Journal of Materials Chemistry, A. Materials for energy and sustainability >Benzodithiophene homopolymers synthesized by Grignard metathesis (GRIM) and Stille coupling polymerizations
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Benzodithiophene homopolymers synthesized by Grignard metathesis (GRIM) and Stille coupling polymerizations

机译:通过格氏(Grignard)复分解(GRIM)和Stille偶联聚合合成的苯并二噻吩均聚物

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摘要

Poly{4,8-bis(95-dodecylthiophene-2-yl)benzo[l,2-b:4,5-6']dithiophene} has been synthesized by both Grignard metathesis (PI) and Stille coupling polymerizations (P2). Polymers PI and P2 were characterized and their optoelectronic properties, charge carrier mobilities, and photovoltaic properties were compared. The field-effect mobilities of the polymers were measured on both untreated and heptadecafluoro-l,l,2,2-tetrahydro-decyl-l-trimethoxysilane (FS) treated organic field effect transistor (OFET) devices. The polymers were also evaluated in bulk heterojunction (BHO) solar cells with [6,6]-phenyl-C_(71)-butyric acid methyl ester (PC71BM) as the acceptor.
机译:聚{4,8-双(95-十二烷基噻吩-2-基)苯并[1,2-b:4,5-6']二噻吩}已通过格氏试剂(PI)和斯蒂勒偶联聚合法(P2)合成。表征了聚合物P1和P2,并比较了它们的光电性能,电荷载流子迁移率和光电性能。在未处理的和七氟-1,1,2,2-四氢癸基-1-三甲氧基硅烷(FS)处理的有机场效应晶体管(OFET)器件上均测量了聚合物的场效应迁移率。还用[6,6]-苯基-C_(71)-丁酸甲酯(PC71BM)作为受体在本体异质结(BHO)太阳能电池中对聚合物进行了评估。

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