...
【24h】

Hidden assumptions in a maximum-entropy method stacking analyses.

机译:最大熵方法堆叠分析中的隐藏假设。

获取原文
获取原文并翻译 | 示例
           

摘要

Two models have been used to describe indefinite self-association (stacking). In the more popular isodesmic model addition of molecules to the growing stack occurs with the same equilibrium constant, while in the attenuated model successive equilibrium constants decrease in value. In an attempt to choose between the two models application was made of the maximum-entropy method. This paper points out that the conclusions drawn from this method are not proven as the application assumed specific limiting values for experimental values of a molecule in the interior of a stack, and these values are not identical in the two models for the two systems considered.
机译:已经使用两种模型来描述不确定的自我关联(堆叠)。在更流行的等渗模型中,以相同的平衡常数将分子添加到生长的堆叠中,而在衰减模型中,连续的平衡常数的值减小。为了在两个模型之间进行选择,应用了最大熵方法。本文指出,该方法得出的结论尚未得到证实,因为该应用程序假设堆内部分子的实验值具有特定的极限值,并且对于两个系统,在两个模型中这些值并不相同。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号