Water diffusion in silicate glasses under natural weathering conditions: evidence from buried medieval stained glasses

Sterpenich J; Libourel G

首页> 外文期刊>Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites >Water diffusion in silicate glasses under natural weathering conditions: evidence from buried medieval stained glasses

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Water diffusion in silicate glasses under natural weathering conditions: evidence from buried medieval stained glasses

机译：自然风化条件下硅酸盐玻璃中的水扩散：来自埋没的中世纪彩色玻璃的证据

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In this study, ion-microprobe analyses of four samples of buried medieval stained-glasses are used to demonstrate that water penetrates into the matrix of pristine glasses at low temperatures, thereby showing that glass alteration is not only a surface process. The diffusion coefficients of water determined from concentration profiles of hydrogen are found to be correlated with the bulk polymerization state of the glass. This observation is discussed with respect to glass structure and implies that ionic exchange between hydrogen and network modifying metal cations is the major process responsible for glass hydration. (c) 2006 Elsevier B.V. All rights reserved.

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《Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites》 |2006年第51期|共6页
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Sterpenich J; Libourel G;
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正文语种 eng
中图分类晶体学;
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chemical durability; ion exchange; diffusion and transport; archaeology; alkali silicates; hydration; SURFACE-LAYERS; DISSOLUTION; KINETICS; MECHANISMS; HYDRATION; MODEL;

机译：化学耐久性;离子交换;扩散和迁移;考古学;碱金属硅酸盐;水化;表面层;溶解;动力学;机理;水合;模型;

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1. Water diffusion in silicate glasses under natural weathering conditions: evidence from buried medieval stained glasses [J] . Sterpenich J, Libourel G Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2006,第50a51期

机译：自然风化条件下硅酸盐玻璃中的水扩散：来自埋没的中世纪彩色玻璃的证据
2. Diffusion nonlinearity in aluminum-boron silicate glasses for ion-exchanged GRIN structures: A simple technique to evaluate diffusion nonlinearity of glasses [J] . A.A. Lipovskii, D.V. Svistunov, D.K. Tagantsev, Optical Materials . 2006,第3期

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3. SILVER DIFFUSION AND COLORATION OF SODA LIME AND BOROSILICATE GLASSES PART 1: EFFECT ON THE TRANSMISSION AND COLORATION OF STAINED GLASSES [J] . ABDELLAH CHORFA, NABIL BELKHIR, FAUSTO RUBIO, Cearmics . 2012,第1期

机译：苏打石灰和硼硅酸盐玻璃的银扩散和污染：第1部分：对染色玻璃的传输和污染的影响
4. Diffusion and Ionic Conduction in Soda-Lime Silicate Glasses and in Alkali Borate Glasses [C] . Helmut Mehrer Diffusion in solids and liquids VI . 2010

机译：苏打石灰硅酸盐玻璃和碱金属硼酸盐玻璃中的扩散和离子传导
5. Water diffusion in silica glass toward understanding of atomistic diffusion mechanism in silicate melts and glasses [D] . 黒田, みなみ 2019

机译：二氧化硅玻璃中的水扩散，以了解硅酸盐熔体和玻璃中的原子扩散机理
6. Microscopic chemical and molecular-biological investigation of the decayed medieval stained window glasses of two Catalonian churches [O] . Guadalupe Piñar, Maite Garcia-Valles, Domingo Gimeno-Torrente, -1

机译：对两个加泰罗尼亚教堂的中世纪彩色玻璃窗进行了显微镜化学和分子生物学研究
7. Stress-enhanced ion diffusion at the vicinity of a crack tip as evidenced by atomic force microscopy in silicate glasses [O] . Celarie, F., Ciccotti, M., Marliere, Christian 2007

机译：硅酸盐玻璃中的原子力显微镜证明，裂纹尖端附近的应力增强了的离子扩散

Water diffusion in silicate glasses under natural weathering conditions: evidence from buried medieval stained glasses

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