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Observation of Meyer-Neldel rule in amorphous thin films of Se100-xSbx in presence of light

机译:光照下Se100-xSbx非晶薄膜中Meyer-Neldel规则的观察

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摘要

In the present paper, we report the thermally activated conductivity in thin films of Se100-xSbx in presence of light of different intensities. We found that the conductivity obeys the Meyer-Neldel rule as the pre-exponential factor depends on activation energy. We also found a strong correlation between prefactor sigma(00) and Meyer-Neldel energy. The origin of the correlation and the MN rule can be described by multiple excitations stimulated by optical phonon energy as described by Yelon and Movaghar. The value of optical phonon energy calculated by experimental data is in good agreement with the YM model which suggests that the optical phonons are the source of the excitation energy in such processes. (c) 2006 Elsevier B.V. All rights reserved.
机译:在本文中,我们报告了在不同强度的光存在下,Se100-xSbx薄膜中的热活化传导率。我们发现电导率遵循Meyer-Neldel规则,因为前指数因子取决于活化能。我们还发现因子sigma(00)和Meyer-Neldel能量之间有很强的相关性。如Yelon和Movaghar所述,可以通过由光子能量激发的多次激发来描述相关性和MN规则的起源。实验数据计算得出的光子能量值与YM模型吻合良好,这表明光子是此类过程中激发能的来源。 (c)2006 Elsevier B.V.保留所有权利。

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