Branching, aggregation, and phase separation during the gelation of tetraethoxysilane

Gommes CJ; Goderis B; Pirard JP; Blacher S

首页> 外文期刊>Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites >Branching, aggregation, and phase separation during the gelation of tetraethoxysilane

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Branching, aggregation, and phase separation during the gelation of tetraethoxysilane

机译：四乙氧基硅烷胶凝过程中的分支，聚集和相分离

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Time-resolved small-angle X-ray scattering is used to follow in situ the structuring of silica sols and gels in various chemical conditions. The acid-catalyzed and base-catalyzed polymerizations of TEOS, as well as the copolymerization of TEOS with organically modified trialkoxysilanes, are followed. The analysis points to the diversity of the mechanisms that govern the structuring of the reacting solutions, and most notably to the important role of physical forces. (C) 2007 Elsevier B.V.All rights reserved.

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《Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites》 |2007年第25期|共5页
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Gommes CJ; Goderis B; Pirard JP; Blacher S;
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正文语种 eng
中图分类晶体学;
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sol-gel; aerogel and solution chemistry; organic-inorganic hybrids; SILICA-GEL FORMATION; TIME-RESOLVED SAXS; GROWTH; XEROGELS;

机译：溶胶-凝胶;气凝胶和溶液化学;有机-无机杂化物;二氧化硅凝胶形成;时间分辨的SAXS;生长;干凝胶;

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机译：四乙氧基硅烷胶凝过程中的分支，聚集和相分离
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Branching, aggregation, and phase separation during the gelation of tetraethoxysilane

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