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Density and microhardness of As-Se glasses and glass fibers

机译:砷硒玻璃和玻璃纤维的密度和显微硬度

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摘要

The density and Vickers microhardness of bulk glasses and glass fibers in the As-Se system have been determined for up to 50% As. Arsenic selenide glasses were batched in an argon atmosphere using high purity arsenic and selenium to produce samples that contained between 5 and 50% As, the balance being Se. The density and hardness of both fibers and bulk glasses increase up to the stoichiometric As2Se3 composition, with the hardness exhibiting a maximum at this composition, in accordance with the average coordination number ([r]) approach. The microhardness of aged fibers of all compositions is found to be higher than the corresponding bulk glass, indicating different structures. Both the density and microhardness of AsSe4 are found to increase rapidly with time after drawing. Density and microhardness results are discussed in terms of quench induced stresses which result from the fiber drawing process, and stress relaxation in arsenic selenide glasses.
机译:已确定As-Se系统中大块玻璃和玻璃纤维的密度和维氏显微硬度最高可达到50%As。使用高纯度砷和硒在氩气气氛中分批注入砷化硒玻璃,以生产出含5%至50%As的样品,其余为Se。纤维和块状玻璃的密度和硬度都增加到化学计量的As2Se3组成,根据平均配位数(r)方法,在该组成下硬度达到最大值。发现所有组成的时效纤维的显微硬度均高于相应的块状玻璃,表明结构不同。发现AsSe4的密度和显微硬度在拉拔后均随时间迅速增加。讨论了密度和显微硬度的结果,这些原因是由纤维拉伸过程引起的淬火引起的应力以及砷化硒玻璃中的应力松弛引起的。

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