The Fe2+/Fe3+-redox equilibrium in 5Na(2)O center dot 15CaO center dot xAl(2)O(3)center dot(80-x)SiO2 (x=5-25) liquids

Wiedenroth A.; Russel C.

首页> 外文期刊>Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites >The Fe2+/Fe3+-redox equilibrium in 5Na(2)O center dot 15CaO center dot xAl(2)O(3)center dot(80-x)SiO2 (x=5-25) liquids

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The Fe2+/Fe3+-redox equilibrium in 5Na(2)O center dot 15CaO center dot xAl(2)O(3)center dot(80-x)SiO2 (x=5-25) liquids

机译：5Na（2）O中心点15CaO中心点xAl（2）O（3）中心点（80-x）SiO2（x = 5-25）液体中的Fe2 + / Fe3 +-氧化还原平衡

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Liquids with the basic compositions of 5Na(2)O . 15CaO . xAl(2)O(3). (80 - x)SiO2 (x = 5, 10,15, 20, 25) doped with 0.25 mol% Fe2O3 were studied by means of square-wave voltammetry in the temperature range 1200-1600 degreesC. With increasing temperature, redox equilibria were shifted to the reduced state. Increasing the alumina concentration from 5 to 10 mol% resulted in an increase in the standard potentials, i.e., in a shift to the reduced state. If the alumina concentration is further increased, the standard potentials decrease again. The latter is caused by the incorporation of alumina in sixfold coordination. (C) 2001 Elsevier Science B.V. All rights reserved. [References: 27]

机译：基本成分为5Na（2）O的液体。 15CaO。 xAl（2）O（3）。通过方波伏安法在1200-1600℃的温度范围内研究了掺有0.25摩尔％Fe2O3的（80-x）SiO2（x = 5，10,15，20，25）。随着温度升高，氧化还原平衡转变为还原态。将氧化铝浓度从5mol％增加到10mol％导致标准电势的增加，即，转变为还原态。如果氧化铝浓度进一步增加，则标准电位再次降低。后者是由于氧化铝以六重配位形式引入。（C）2001 Elsevier Science B.V.保留所有权利。 [参考：27]

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《Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites》 |2001年第1期|共8页
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Wiedenroth A.; Russel C.;
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1. The Fe2+/Fe3+-redox equilibrium in 5Na(2)O center dot 15CaO center dot xAl(2)O(3)center dot(80-x)SiO2 (x=5-25) liquids [J] . Wiedenroth A., Russel C. Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2001,第1期

机译：5Na（2）O中心点15CaO中心点xAl（2）O（3）中心点（80-x）SiO2（x = 5-25）液体中的Fe2 + / Fe3 +-氧化还原平衡
2. Voltammetric studies of Fe2+/Fe3+-redox equilibria in some Na2O center dot CaO center dot Al2O3 center dot SiO2 liquids [J] . de Strycker J., von der Gonna G., Russel C., Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2000,第2a3期

机译：某些Na2O中心点CaO中心点Al2O3中心点SiO2液体中Fe2 + / Fe3 +-氧化还原平衡的伏安研究
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The Fe2+/Fe3+-redox equilibrium in 5Na(2)O center dot 15CaO center dot xAl(2)O(3)center dot(80-x)SiO2 (x=5-25) liquids

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