Fourth-order rotational corrections to the effective dipole moments of nonrigid asymmetric rotors

Starikov VI.

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Fourth-order rotational corrections to the effective dipole moments of nonrigid asymmetric rotors

机译：非刚性非对称转子有效偶极矩的四阶旋转校正

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An expression for the fourth-order rotational correction terms of the effective dipole moments of nonrigid asymmetric rotors has been derived using the method of contact transformation. The treatment takes into account the large-amplitude bending motion. The correction terms have been calculated for the different bending states of the H2O molecule. A poor convergence of the rotational series for this molecule has been obtained and some different nonpolynomial forms for these series, obtained by different summation methods, have been proposed and tested, (C) 2001 Academic Press. [References: 13]

机译：使用接触变换的方法，得出了非刚性非对称转子有效偶极矩的四阶旋转校正项的表达式。该处理考虑了大幅度弯曲运动。已针对H2O分子的不同弯曲状态计算了校正项。已经获得了该分子旋转序列的较弱收敛性，并且已经提出并测试了通过不同的求和方法获得的这些序列的一些不同的非多项式形式，（C）2001 Academic Press。 [参考：13]

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《Journal of Molecular Spectroscopy》 |2001年第2期|共6页
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Starikov VI.;
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正文语种 eng
中图分类光学;
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1. Fourth-order rotational corrections to the effective dipole moments of nonrigid asymmetric rotors [J] . Starikov VI. Journal of Molecular Spectroscopy . 2001,第2期

机译：非刚性非对称转子有效偶极矩的四阶旋转校正
2. Induction correction of the molecular dipole moment for rotation of two or three dihedral angles [J] . Holt A, Karlstrom G Journal of Computational Chemistry: Organic, Inorganic, Physical, Biological . 2008,第12期

机译：分子偶极矩的感应校正，可旋转两个或三个二面角
3. v(2)-Dependences of the Rotational Contributions to the Effective Dipole Moment of the H2O Molecule and Their Effect on the Broadening and Shift of Lines Induced by the Pressure of Buffer Gases [J] . Starikov V. I. Optics and Spectroscopy . 2019,第2期

机译：V（2） - 旋转贡献对H2O分子的有效偶极力矩的依赖性及其对缓冲气体压力诱导的线的扩大和转移的影响
4. Quantum corrections to a semiclassical approximation for describing vibration-rotation spectra of nonrigid molecules: the example of an asymmetric top [C] . Author(s): A.S. Skalozub Ukrainian State Univ. of Chemical Technology Dnepropetrovsk Ukraine, Artyom Y. Tsaune Ukrainian State Univ. of Chemical Technology Dniepropetrovsk Ukraine. 12th Symposium and School on High-Resolution Molecular Spectroscopy . 1997

机译：用于描述非刚性分子振动旋转光谱的半经典近似的量子校正：不对称顶部的示例
5. CYCLOTRIBORAZANE: ENTHALPY OF SUBLIMATION, DIPOLE MOMENT, DIPOLE-DIPOLE INTERACTION ENERGY, INFRARED AND RAMAN SPECTRA, AND PROBABLE FREQUENCY ASSIGNMENT. [D] . LEAVERS, DONALD RICHARD. 1971

机译：环硼硼烷：增感，偶极矩，偶极-偶极相互作用能，红外和拉曼光谱以及可能的频率分配等。
6. Uniaxial transition dipole moments in semiconductor quantum rings caused by broken rotational symmetry [O] . Nicolai F. Hartmann, Matthew Otten, Igor Fedin, -1

机译：破坏的旋转对称性导致半导体量子环中的单轴跃迁偶极矩
7. DIPOLE MOMENTS AND NON-COVALENT BONDING IN GAS PHASE MOLECULES VIA ROTATIONALLY RESOLVED ELECTRONIC SPECTROSCOPY: BEYOND THE RIGID ROTOR [O] . Miller Diane 2010

机译：通过旋转分辨电子光谱在气相分子中的偶极矩和非共价键合：超越刚性转子
8. Absorption of IR Radiation by H2O and Other Atmospheric Species. I. Dipole Autocorrelation Function for Far-Wing Pressure Broadening. II. Updating the AFGL Line Parameters Atlas for Asymmetric Rotor Molecules [R] . Davies, R. W., Gamache, R. R. 1981

机译：H2O和其他大气物种对红外辐射的吸收。 I.用于远翼压力展宽的偶极自相关函数。 II。更新非对称转子分子的aFGL线参数图谱

Fourth-order rotational corrections to the effective dipole moments of nonrigid asymmetric rotors

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