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New titanate matrices for immobilization of REE-actinide high-level waste

机译:用于固定tit-act系元素高放废物的新型钛酸酯基质

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摘要

The phases with different structures formed in the series REE2TixZr2-xO7 (x = 0-2) are considered as potential high-level waste (HLW) forms. Matrices were synthesized by cold pressing and sintering. The ceramics were studied by XRD, SEM/EDS, TEM, XAFS. The sample based on monoclinic REE2Ti2O7 was irradiated by Kr2+ (1 MeV). The appearance of the additional monoclinic compound to pyrochlore is observed in the samples at x > 0.8. The monoclinic REE2Ti2O7 is characterized by high isomorphic capacity with respect to REEs. Its radiation resistance is close to Ti-pyrochlores. Monoclinic REE titanate requires further examination as potential host phase for HLW immobilization.
机译:REE2TixZr2-xO7系列(x = 0-2)中形成的具有不同结构的相被认为是潜在的高放废物(HLW)形式。通过冷压和烧结合成基质。通过XRD,SEM / EDS,TEM,XAFS研究了陶瓷。用Kr2 +(1 MeV)辐照基于单斜REE2Ti2O7的样品。在x> 0.8的样品中观察到了烧绿石中另一种单斜晶系化合物的出现。单斜REE2Ti2O7的特征是相对于REE具有较高的同构能力。它的抗辐射性接近于烧绿石。单斜晶系钛酸酯需要进一步检查,以作为固定HLW的潜在宿主期。

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