CRYSTAL STRUCTURE REFINEMENT OF fac-Co(NH2C2H4O)(3)center dot 3H(2)O: OCTAHEDRON OR TRIGONAL PRISM?

Virovets AV; Mikhailenko YA; Peresypkina EV; Tkachev SV; Cherkasova TG

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CRYSTAL STRUCTURE REFINEMENT OF fac-Co(NH2C2H4O)(3)center dot 3H(2)O: OCTAHEDRON OR TRIGONAL PRISM?

机译：fac-Co（NH2C2H4O）（3）中心点3H（2）O的晶体结构细化：八面体或三角棱镜？

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The compound fac-[Co(NH2CH2CH2O)(3)]center dot 3H(2)O (I) was synthesized and its crystal structure determined. Crystal data for C6H24CoN3O6: a = 14.5236(3) angstrom, c = 4.9346(2) angstrom, V = 901.43(5) angstrom(3), T = 90 K, space group R3, Z = 3, rho(calc) = 1.620 g/cm(3). In the complex, the octahedral environment of the Co(III) atom is formed by three monoethanolamine ligands using N and O atoms. The structure is disordered in such a way that the two oppositely orientated CoN3O3 octahedra are superimposed on each other at an angle.

机译：合成了化合物fac- [Co（NH2CH2CH2O）（3）]中心点3H（2）O（I），并确定了其晶体结构。 C6H24CoN3O6的晶体数据：a = 14.5236（3）埃，c = 4.9346（2）埃，V = 901.43（5）埃（3），T = 90 K，空间群R3，Z = 3，rho（calc）= 1.620克/厘米（3）。在该配合物中，Co（III）原子的八面体环境是由使用N和O原子的三个单乙醇胺配体形成的。这种结构是无序的，使得两个方向相反的CoN3O3八面体以一定角度相互叠加。

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来源
《Journal of structural chemistry》 |2010年第1期|共4页
作者
Virovets AV; Mikhailenko YA; Peresypkina EV; Tkachev SV; Cherkasova TG;
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正文语种 eng
中图分类结构化学;
关键词
cobalt; crystal structure; hydrogen bonds; disorder;

机译：钴;晶体结构;氢键;无序;

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CRYSTAL STRUCTURE REFINEMENT OF fac-Co(NH2C2H4O)(3)center dot 3H(2)O: OCTAHEDRON OR TRIGONAL PRISM?

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