DICHLOROTRIETHYLPHOSPHINE-[N-FORMYL-N,N′-bis(3,4-DIMETHOXY)BENZYL-TRIMETHYL-ENEDIAMINE]PLATINUM(II)

O. ?ahin; E. ?. ?zcan; N. Gürbüz; ?. ?zdemir; O. Büyükgüng?r

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DICHLOROTRIETHYLPHOSPHINE-[N-FORMYL-N,N′-bis(3,4-DIMETHOXY)BENZYL-TRIMETHYL-ENEDIAMINE]PLATINUM(II)

机译：二氯三乙基膦-[N-甲酰基-N，N'-双（3,4-二甲氧基）苄基-三甲基-乙二胺]铂（II）

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By treatment of 1,3-bis(3,4-dimethoxybenzyl)-3,4,5,6-tetrahydropyrimidinium chloride (1) with KOBu~t and [PtCl_2(PEt_3)_2]_2 N-coordinated platinum complex (2) is obtained. The Pt atom is coordinated in square planar arrangements by two chloride ions in a trans-configuration, the N-formyl-N,N ′-bisaryltrimethylenediamine nitrogen atom, and the phosphine P atom. An extensive three-dimensional network of three C–H?O hydrogen bonds, two C–H?π and one π?π interactions are responsible for the crystal stabilization. Intermolecular hydrogen bonds and C–H?π interactions produce R_2~2 (6), R_2~2 (22), R_2~2 (24), R_3~3 (23), R_4~4 (26), and R_4~4 (32) rings.

机译：通过用KOBu〜t和[PtCl_2（PEt_3）_2] _2 N配位的铂络合物（1）处理1,3-双（3,4-二甲氧基苄基）-3,4,5,6-四氢嘧啶氯化铵（1）获得。 Pt原子在正方形平面排列中由两个反式构型的氯离子，N-甲酰基-N，N'-双芳基三亚甲基二胺氮原子和膦P原子配位。由三个C–H2O氢键，两个C–H2π和一个π？π相互作用构成的广泛三维网络负责晶体的稳定作用。分子间氢键和C–H？π相互作用产生R_2〜2（6），R_2〜2（22），R_2〜2（24），R_3〜3（23），R_4〜4（26）和R_4〜4 （32）响。

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《Journal of structural chemistry》 |2014年第4期|共6页
作者
O. ?ahin; E. ?. ?zcan; N. Gürbüz; ?. ?zdemir; O. Büyükgüng?r;
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正文语种 eng
中图分类结构化学;
关键词
tetrahydropyrimidine; N-formyl-N; N ′-bisaryltrimethylenediamine; Pt(II) complex; X-ray diffraction analysis.;

机译：四氢嘧啶;N-甲酰基-N;N′-双芳基三亚甲基二胺;Pt（II）配合物;X射线衍射分析。;

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1. DICHLOROTRIETHYLPHOSPHINE-[N-FORMYL-N,N′-bis(3,4-DIMETHOXY)BENZYL-TRIMETHYL-ENEDIAMINE]PLATINUM(II) [J] . O. ?ahin, E. ?. ?zcan, N. Gürbüz, Journal of structural chemistry . 2014,第4期

机译：二氯三乙基膦-[N-甲酰基-N，N'-双（3,4-二甲氧基）苄基-三甲基-乙二胺]铂（II）
2. Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(III)] [J] . Li H.-Q., Liu J.-F., Xu X.-D., Acta Crystallographica Section E: Crystallographic Communications . 2010,第3期

机译：四（μ-3,4-二甲氧基苯基乙酸）双[（3,4-二甲氧基苯基乙酸）（1,10-菲咯啉）dy（III）]
3. Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(III)] [J] . Li H.-Q., Liu J.-F., Xu X.-D., Acta Crystallographica Section E: Crystallographic Communications . 2010,第3期

机译：四（μ-3,4-二甲氧基苯基乙酸）双[（3,4-二甲氧基苯基乙酸）（1,10-菲咯啉）dy（III）]
4. Electrodeposition of Platinum in Some Amide-Type Ionic Liquids Containing Bis(acetylacetonato)platinum(II) [C] . Sharmin Sultana, Naoki Tachikawa, Kazuki Yoshii, PRiME Joint International Meeting of the Electrochemical Society, the Electrochemical Society of Japan, and the Korean Electrochemical Society . 2016

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5. Part I. Alkaloidal constituents of selected fractions of Thalictrum angustifolium L. and Thalictrum wangii Boivin (Ranunculaceae). Part II. A revision of the structure of thalprzewalskiinone. The synthesis of 2-methyl-6,7-dimethoxy-3'-methoxy-4'-hydroxyoxobenzylisoquinoline and 2-methyl-6,7-dimethoxy-3'-hydroxy-4'-methoxyoxobenzylisoquinoline. [D] . Al-Howiriny, Tawfeq Abdullah. 2000

机译：第一部分。拟南芥和拟南芥（Ranunculaceae）的选定部分的生物碱成分。第二部分thalprzewalskiinone结构的修订。 2-甲基-6,7-二甲氧基-3'-甲氧基-4'-羟基氧苄基异喹啉和2-甲基-6,7-二甲氧基-3'-羟基-4'-甲氧基氧苄基异喹啉的合成。
6. N-(3,4-Difluorophenyl)-3,4-dimethoxybenzenesulfonamide [O] . Hyon Pil You, Byung Hee Han, Sung Kwon Kang, 2015

机译：N-（3,4-二氟基）-3,4-二甲氧基苯磺酰胺
7. Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(III)] [O] . Liu, Jian-Feng, Xu, Xue-Dan, Li, Hua-Qiong, 2010

机译：四（μ-3,4-二甲氧基苯基乙酸）双 [（3,4-二甲氧基苯基乙酸）（1,10-菲咯啉）phen（III）]

DICHLOROTRIETHYLPHOSPHINE-[N-FORMYL-N,N′-bis(3,4-DIMETHOXY)BENZYL-TRIMETHYL-ENEDIAMINE]PLATINUM(II)

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