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首页> 外文期刊>Journal of Photochemistry and Photobiology, A. Chemistry >Triplet-triplet absorption of some organic molecules determined by picosecond laser excitation and time-delayed picosecond light continuum probing
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Triplet-triplet absorption of some organic molecules determined by picosecond laser excitation and time-delayed picosecond light continuum probing

机译:皮秒激光激发和皮秒延时光连续探测确定的某些有机分子的三重态-三重态吸收

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摘要

The triplet-triplet absorption cross-section spectra of eosin Y, erythrosin B, rose bengal and C_70 are determined in the wavelength range from 390 to 1600 nm. The T_1 triplet state is populated by S_1->T_1 intersystem crossing after singlet state excitation with intense picosecond pump pulses (wavelength 527 nm, duration 6 ps). The triplet-triplet absorption is probed with picosecond spectral light continua passing the samples after excited singlet state relaxation (time delay 20 ns). Absolute triplet-triplet absorption cross-sections are obtained by numerical simulation of the absorption dynamics.
机译:曙红Y,赤藓红B,玫瑰红和C_70的三重态三重态吸收截面光谱是在390至1600 nm的波长范围内测定的。在具有强烈的皮秒泵浦脉冲(波长527 nm,持续时间6 ps)的单重态激发后,S_1-> T_1系统间交叉填充了T_1三重态。在激发单重态弛豫(时间延迟20 ns)之后,通过皮秒的光谱光连续波探测三重态三重态吸收。通过吸收动力学的数值模拟可以获得绝对的三重态-三重态三重吸收截面。

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