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A chemist's approach to superconductivity

机译:化学家的超导方法

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摘要

Over the last few years, we have studied the phenomenon of superconductivity from a chemist's point of view. Starting from the special chemical bonding picture of some rare earth carbides and carbide halides, a general viewpoint on the origin of superconductivity was proposed [1]. This so-called "flat band steep band" scenario is based on the chemical origin of pairwise attractive interaction between conduction electrons. The flat bands provide a vanishing Fermi velocity for some conduction electrons in the normal conducting state. Provided these electrons get spin-paired the scenario of Bose condensation as described by London is met [2]. The "steep band" provides a mobile electronic reservoir and suppresses the instability of a structure. This view is formally similar to a physical model based on the interplay of itinerant electrons in a wide band with local pairs of electrons in a narrow band [3]. However, in extracting the flat hand/steep band features from calculated band structures we address the specific chemical bonding in actual superconductors.
机译:在过去的几年中,我们从化学家的角度研究了超导现象。从一些稀土碳化物和碳化物卤化物的特殊化学键合图开始,提出了关于超导起源的一般观点[1]。这种所谓的“平带陡带”情况是基于导电电子之间成对吸引相互作用的化学起源。平坦带为正常导电状态下的某些导电电子提供了消失的费米速度。只要这些电子自旋配对,就可以满足伦敦所描述的玻色凝聚的情况[2]。 “陡带”提供了可移动的电子储存器并抑制了结构的不稳定性。这种观点在形式上类似于基于宽带中的巡回电子与窄带中的局部电子对相互作用的物理模型[3]。但是,在从计算出的能带结构中提取平坦的手/陡带特征时,我们要解决实际超导体中的特定化学键。

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