Synthesis, characteristic, catalytic and antimicrobial activities of imidazolo substituted benzylidene imines with ruthenium(II) complexes

K. P. Balasubramian; V. V. Raju; V. Chinnusamy

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Synthesis, characteristic, catalytic and antimicrobial activities of imidazolo substituted benzylidene imines with ruthenium(II) complexes

机译：咪唑基取代亚苄基亚胺与钌（II）配合物的合成，特征，催化和抗菌活性

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The synthesis and characterization of several hexa-coordinated Ru~(II) complexes of the type [RuCI(CO)(EPh3)2(L)] (E = P or As; L = monobasic bidentate anion) are reported. IR, electronic, ~1H NMR, ~(31)P NMR and catalytic activity of the complexes are discussed. An octahedral geometry has been tentatively proposed for all these complexes. The new complexes exhibit catalytic activity for the addition of benzyl alcohol and cyclohexanol in the presence of N-methylmorpholine-N-oxide as co-oxidant. The new complexes were also exhibited antimicrobial investigations.

机译：报道了几种[RuCl（CO）（EPh3）2（L）]（E = P或As; L =一元二齿阴离子）六价配位的Ru〜（II）配合物的合成和表征。讨论了IR，电子，〜1H NMR，〜（31）P NMR和配合物的催化活性。已经为所有这些复合物初步提出了八面体几何形状。在N-甲基吗啉-N-氧化物作为助氧化剂的存在下，新的配合物表现出添加苄醇和环己醇的催化活性。新的复合物也进行了抗菌研究。

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来源
《Journal of the Indian Chemical Society》 |2009年第6期|共7页
作者
K. P. Balasubramian; V. V. Raju; V. Chinnusamy;
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正文语种 eng
中图分类化学;
关键词
Ruthenium(II) complex; benzylidene imine; synthesis; imidazolo;

机译：钌（II）配合物;亚苄基亚胺;合成;咪唑啉;

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1. Synthesis, characteristic, catalytic and antimicrobial activities of imidazolo substituted benzylidene imines with ruthenium(II) complexes [J] . K. P. Balasubramian, V. V. Raju, V. Chinnusamy Journal of the Indian Chemical Society . 2009,第6期

机译：咪唑基取代亚苄基亚胺与钌（II）配合物的合成，特征，催化和抗菌活性
2. Synthesis, characterization, electrochemical, catalytic and antimicrobial activity studies of hydrazone Schiff base ruthenium(II) complexes [J] . N. Thilagavathi, A. Manimaran, N. Padma Priya Applied Organometallic Chemistry . 2010,第4期

机译：Sch席夫碱钌（II）配合物的合成，表征，电化学，催化和抗菌活性研究
3. Synthesis, characterization, electrochemical, catalytic and antimicrobial activity studies of hydrazone Schiff base ruthenium(II) complexes [J] . N. Thilagavathi, A. Manimaran, N. Padma Priya, Applied Organometallic Chemistry . 2010,第4期

机译：Sch席夫碱钌（Ⅱ）配合物的合成，表征，电化学，催化和抗菌活性研究
4. Chitosan- Copper(II) , Zinc(II) and Ferric(II) Complexes as Antimicrobial Agent: Synthesis, Characterization and Structure- Activity Study [C] . Xiaohui Wang, Yumin Du, Fei Huang Polymeric Materials: Science Engineering Symposia . 2005

机译：壳聚糖 - 铜（II），锌（II）和铁（II）复合物作为抗微生物剂：合成，表征和结构 - 活性研究
5. The synthesis and catalytic activity of isoelectronic rhodium(III) and ruthenium(II) complexes for cyclopropanation [D] . Eveland, Renee Ann 2000

机译：等电子铑（III）和钌（II）配合物的环丙烷化反应
6. Synthesis Reactivity and Catalytic Transfer HydrogenationActivity of Ruthenium Complexes Bearing NNN Tridentate Ligands: Influenceof the Secondary Coordination Sphere [O] . Jing Shi, Bowen Hu, Xiangyang Chen, 2017

机译：合成反应性和催化转移加氢带有NNN三齿配体的钌配合物的活性：影响二级协调领域
7. Synthesis, Characteristic, Catalytic and Antimicrobial activities of Imidazolo substituted Benzylidene imines with Ruthenium (III) complexes [O] . K. P. BALASUBRAMANIAN, V. V. RAJU, V. CHINNUSAMY 2017

机译：咪唑取代苄基酰亚胺酰亚胺酰亚胺与钌（III）复合物的合成，特征，催化和抗微生物活性

Synthesis, characteristic, catalytic and antimicrobial activities of imidazolo substituted benzylidene imines with ruthenium(II) complexes

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