SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL STRUCTURES OF COPPER(II) AND NICKEL(II) COMPLEXES WITH SCHIFF BASES

LIU H.Y.

首页> 外文期刊>Координационная химия >SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL STRUCTURES OF COPPER(II) AND NICKEL(II) COMPLEXES WITH SCHIFF BASES

【24h】

SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL STRUCTURES OF COPPER(II) AND NICKEL(II) COMPLEXES WITH SCHIFF BASES

机译：席夫碱的铜（II）和镍（II）配合物的合成，表征和X射线晶体结构

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

New copper(II) complexes, [Cu_2L~1L~2] · ClO_4 (I) and [Ni(L~3)_2] (II), where L~1 is the mono-anionic form of 2-[1-(2-emthylaminoethylimino)ethyl]phenol, L~2 is the dianionic form of N,N'-ethylene-bis(2-hydroxyacetophenonylideneimine), L~3 is the mono-anionic form of 2-(1-iminoethyl)phenol, were prepared and characterized using elemental analysis, FT-IR spectroscopy, and X-ray single-crystal diffraction. In complex I, the Cu(1) atom is coordinated by the NNO tridentate ligand L~1 and the two phenolate O atoms of L~2, forming a square pyramidal geometry. The Cu(2) atom in complex I is coordinated by the NNOO tetradenate ligand L~2, forming a square planar geometry. The Ni atom in complex II is coordinated by two phenolate O and two imine N atoms from two ligands L~3, forming a square planar geometry. In the crystal structure of I, the perchlorate anions are linked to the dinuclear copper(II) complex cations through intermolecular N—H···O hydrogen bonds. In the crystal structure of II, the mononuclear nickel complex molecules are linked through intermolecular N—H···O hydrogen bonds, forming a trimer.

机译：新的铜（II）配合物，[Cu_2L〜1L〜2]·ClO_4（I）和[Ni（L〜3）_2]（II），其中L〜1是2- [1-（ 2-乙基氨基乙基亚氨基）乙基]酚，L〜2是N，N'-亚乙基-双（2-羟基乙酰苯甲叉亚胺）的二价阴离子形式，L〜3是2-（1-亚氨基乙基）苯酚的单阴离子形式。使用元素分析，FT-IR光谱和X射线单晶衍射制备和表征。在配合物I中，Cu（1）原子由NNO三齿配体L〜1和L〜2的两个酚O原子配位，形成方形锥体。配合物I中的Cu（2）原子由NNOO四齿配体L〜2配位，形成方形平面几何形状。配合物II中的Ni原子由两个配体L〜3的两个酚盐O和两个亚胺N原子配位，形成方形平面几何形状。在I的晶体结构中，高氯酸根阴离子通过分子间的NH···O氢键与双核铜（II）络合物阳离子连接。在II的晶体结构中，单核镍络合物分子通过分子间的NH···O氢键连接，形成三聚体。

著录项

来源
《Координационная химия》 |2013年第8期|共5页
作者
LIU H.Y.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. Synthesis, characterization, X-ray crystal structures and antibacterial activities of Schiff base ligands derived from allylamine and their vanadium(IV), cobalt(III), nickel(II), copper(II), zinc(II) and palladium(II) complexes [J] . Rudbari Hadi Amiri, Iravani Mohammad Reza, Moazam Vahid, Journal of Molecular Structure . 2016,第Null期

机译：烯丙基胺及其钒（IV），钴（III），镍（II），铜（II），锌（II）和钯（II）衍生的席夫碱配体的合成，表征，X射线晶体结构和抗菌活性复合体
2. Synthesis, Characterization, and X-ray Crystal Structures of Copper(II) and Nickel(II) Complexes with Schiff Base~1 [J] . H. Y. Liu Russian Journal of Coordination Chemistry . 2013,第8期

机译：席夫碱〜1的铜（II）和镍（II）配合物的合成，表征和X射线晶体结构
3. SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL STRUCTURES OF COPPER(II) AND NICKEL(II) COMPLEXES WITH SCHIFF BASES [J] . LIU H.Y. Координационная химия . 2013,第8期

机译：席夫碱的铜（II）和镍（II）配合物的合成，表征和X射线晶体结构
4. Highly polarizable metallic complexes for nonlinear optics copper(II) andnickel(II) complexes of bis(salicylaldiminato) Schiff base, [C] . Abdalla M. Darwish, Alabama AM Univ., Huntsville, Nonlinear Optical Properties of Organic Materials IX . 1996

机译：高极化金属配合物，用于双（水杨基铝亚胺）Schiff碱的非线性光学铜（II）和镍（II）配合物，
5. Synthesis and Characterization of Nickel(II) Complexes of Schiff Bases and Other Ligands as Potential Models for Molecular Magnets. [D] . Ayikoe, Kouassi. 2011

机译：席夫碱和其他配体的镍（II）配合物的合成和表征，作为分子磁体的潜在模型。
6. Heterometallic ZnII–LnIII–ZnII Schiff Base Complexes with Linear or Bent Conformation—Synthesis Crystal Structures Luminescent and Magnetic Characterization [O] . Barbara Miroslaw, Beata Cristóvão, Zbigniew Hnatejko 2018

机译：具有线性或弯曲构型的杂金属ZnII–LnIII–ZnII Schiff碱配合物-合成晶体结构发光和磁性表征
7. Synthesis and characterization of cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II) complexes of benzyl N-1-(thiophen-2-yl)ethylidene hydrazine carbodithioate and benzyl N-1-(thiophen-3-yl)ethylidene hydrazine carbodithioate and the X-ray crystal structure of bis{benzyl N-1-(thiophen-2-yl)ethylidene hydrazine carbodithioate}nickel(II) [O] . Mun-Hoe Eddy Chan, Karen A. Crouse, M. Ibrahim M. Tahir, 2008

机译：苄基N- 1-（硫氰酸-2-基）乙基肼碳腈和苄基甲基肼和苄基（II），镍（II），镍（II），铜（II），锌（II），锌（II）和镉（II）复合物的合成及表征 - 1-（噻吩-3-基）乙基肼碳化碳酸肼和双{苄基-1-（苯甲烯-2-基）乙基肼碳脱硫酶}镍（II）
8. CRYSTAL STRUCTURES OF NICKEL AND COPPER COMPOUNDS PART I. TWO BIS COMPLEXES OF 2.2’-IMINOBIS (ACETAMIDOXIME) PART II REGULAR OCTAHEDRAL COPPER (II) COMPLEXES [R] . DAVID LAWRENCE CULLEN 1969

机译：镍和铜化合物的晶体结构第一部分2.2'-亚氨基（乙酰氨基）第二部分正二甲基铜（Ⅱ）配合物的两个双配合物

SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL STRUCTURES OF COPPER(II) AND NICKEL(II) COMPLEXES WITH SCHIFF BASES

摘要

著录项

相似文献

相关主题

期刊订阅