Preparation and characterization of molybdenum hexacarbonyl encapsulated in polystyrene and its application as an efficient and reusable catalyst for epoxidation of alkenes with tert-BuOOH

Shahram Tangestaninejad; Majid Moghadam; Valiollah Mirkhani

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Preparation and characterization of molybdenum hexacarbonyl encapsulated in polystyrene and its application as an efficient and reusable catalyst for epoxidation of alkenes with tert-BuOOH

机译：封装在聚苯乙烯中的六羰基钼的制备，表征及其作为叔丁醇对烯烃环氧化的有效且可重复使用的催化剂的应用

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Molybdenum hexacarbonyl encapsulated in polystyrene, Mo(CO)6@PS, was prepared by suspension polymerization of styrene and divinylbenzene in the presence of Mo(CO)6. This catalyst was found as an efficient catalyst for epoxidation of a wide variety of alkenes, including aromatic and aliphatic terminal ones using tert-butyl hydroperoxide as oxidant. This new heterogenized molybdenum carbonyl catalyst could be easily recovered by simple filtration and was reused ten consecutive times without loss of its catalytic activity.

机译：通过在Mo（CO）6的存在下苯乙烯和二乙烯基苯的悬浮聚合反应制得封装在聚苯乙烯Mo（CO）6 @ PS中的六羰基钼。发现该催化剂是使用叔丁基过氧化氢作为氧化剂对多种烯烃进行环氧化的有效催化剂，包括芳族和脂族端基。这种新型的异质羰基钼钼催化剂可通过简单过滤轻松回收，并连续十次重复使用，而不会损失其催化活性。

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《Comptes Rendus Chimie》 |2011年第6期|共7页
作者
Shahram Tangestaninejad; Majid Moghadam; Valiollah Mirkhani;
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正文语种 eng
中图分类化学;
关键词
Encapsulation; Molybdenum hexacarbonyl; Epoxidation; Polystyrene; TBHP;

机译：包封六羰基钼环氧聚苯乙烯TBHP;

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1. Preparation and characterization of molybdenum hexacarbonyl encapsulated in polystyrene and its application as an efficient and reusable catalyst for epoxidation of alkenes with tert-BuOOH [J] . Shahram Tangestaninejad, Majid Moghadam, Valiollah Mirkhani Comptes Rendus Chimie . 2011,第6期

机译：封装在聚苯乙烯中的六羰基钼的制备，表征及其作为叔丁醇对烯烃环氧化的有效且可重复使用的催化剂的应用
2. Molybdenum hexacarbonyl supported on amine modified multi-wall carbon nanotubes: an efficient and highly reusable catalyst for epoxidation of alkenes with tert-butyl hydroperoxide [J] . Majid Moghadam, Shahram Tangestaninejad, Valiollah Mirkhani Applied Organometallic Chemistry . 2010,第10期

机译：胺修饰的多壁碳纳米管上负载的六羰基钼：一种高效且高度可重复使用的催化剂，用于用氢过氧化叔丁基对烯烃进行环氧化
3. Molybdenum hexacarbonyl supported on amine modified multi-wall carbon nanotubes: an efficient and highly reusable catalyst for epoxidation of alkenes with tert-butylhydroperoxide [J] . Majid Moghadam, Shahram Tangestaninejad, Valiollah Mirkhani, Applied Organometallic Chemistry . 2010,第10期

机译：胺修饰的多壁碳纳米管上负载的六羰基钼：一种高效且高度可重复使用的催化剂，用于用叔丁基过氧化氢对烯烃进行环氧化
4. A New Generation of Titanosilicate Catalyst: Preparation and Application to Liquid-Phase Epoxidation of Alkenes [C] . Peng Wu, Takashi Tatsumi Asia-Pacific Congress on Catalysis . 2003

机译：新一代钛硅酸盐催化剂：制备和应用于烯烃的液相环氧化
5. Preparation, characterization and hydrodesulfurization (HDS) activity of molybdenum/SBA-15 catalysts with increased and well dispersed molybdenum species [D] . Jamiu, Zakariyah Abdulkareem 2012

机译：钼种类增加且分散均匀的Mo / SBA-15催化剂的制备，表征和加氢脱硫（HDS）活性
6. Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis [O] . Steven J. Malcolmson, Simon J. Meek, Elizabeth S. Sattely, -1

机译：用于对映选择性烯烃复分解的高效钼基催化剂
7. Polystyrene-supported 1-methylimidazolium tetrachloro ferrate: Synthesis, characterization, and application as an efficient and reusable heterogeneous catalyst for one-pot synthesis of 4h-chromene derivatives in aqueous media [O] . N. Taheri, M. Fallah-Mehrjardi, S. Sayyahi 2018

机译：聚苯乙烯支持的1-甲基咪唑鎓四氯甲酸乙酯：合成，表征和应用作为一种高效且可重复使用的非均相催化剂，用于一罐在水性介质中的4H-铬衍生物的1罐合成
8. Supercritical fluid solubilization of catalyst precursors: The solubility and phase behavior of molybdenum hexacarbonyl in supercritical carbon dioxide and applications to the direct liquefaction of coal. [R] . Warzinski, R. P., Lee, C. H., Holder, G. D. 1991

机译：催化剂前体的超临界流体溶解：六羰基钼在超临界二氧化碳中的溶解度和相行为以及在煤的直接液化中的应用。

Preparation and characterization of molybdenum hexacarbonyl encapsulated in polystyrene and its application as an efficient and reusable catalyst for epoxidation of alkenes with tert-BuOOH

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