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Mineral oxides and layered minerals in combination with itaconic acid as coagents for peroxide crosslinking of hydrogenated acrylonitrile-butadiene elastomer

机译:矿物氧化物和层状矿物与衣康酸的组合作为氢化丙烯腈-丁二烯弹性体的过氧化物交联剂

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摘要

The aim of this work was to study the activity of nanosized calcium and magnesium oxides and layered minerals (boehmite, hydrotalcite) as coagents in the crosslinking of hydrogenated acrylonitrile-butadiene elastomer (HNBR) with dicumyl peroxide. The surfaces of the mineral oxides and layered minerals were modified with unsaturated acid (itaconic acid) to ensure their activity during the crosslinking process. The efficiency of modification process was estimated, based on thermogravimetric analysis and zeta potential measurements of obtained coagents. In this article, we discuss the effect of coagents on the crosslinking density and mechanical properties of vulcanisates. Application of nanosized mineral oxides and layered minerals together with itaconic acid decreased the optimal vulcanisation time of rubber compounds and improved the crosslinks density as well as the tensile strength of the vulcanisates due to formation of additional ionic crosslinks in the elastomer network. It is important from technological reasons.
机译:这项工作的目的是研究在氢化丙烯腈-丁二烯弹性体(HNBR)与过氧化二枯基的交联中,纳米级氧化钙和镁氧化物以及层状矿物(勃姆石,水滑石)作为助剂的活性。矿物氧化物和层状矿物的表面用不饱和酸(衣康酸)改性,以确保它们在交联过程中的活性。基于获得的助剂的热重分析和ζ电势测量,估计了改性过程的效率。在本文中,我们讨论了助剂对硫化橡胶交联密度和机械性能的影响。由于在弹性体网络中形成了额外的离子交联,因此将纳米级矿物氧化物和层状矿物与衣康酸一起使用可减少橡胶化合物的最佳硫化时间,并改善了交联密度以及硫化胶的拉伸强度。由于技术原因,这一点很重要。

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