An unsupported uranium-rhenium complex prepared by alkane elimination

Gardner B.M.; McMaster J.; Moro F.; Lewis W.; Blake A.J.; Liddle S.T.

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An unsupported uranium-rhenium complex prepared by alkane elimination

机译：通过消除烷烃制得的无载体铀-complex络合物

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An unsupported uranium-rhenium bond has been prepared by alkane elimination by treatment of a cyclometallated alkyl uranium triamidoamine complex with rhenocene hydride (see scheme). DFT analysis reveals σ and π combinations in the U-Re bond, but the rhenium contributions dominate and an atoms-in-molecules analysis reveals a closed-shell, predominantly ionic uranium-rhenium interaction.

机译：通过用rh茂金属氢化物处理环金属化的烷基铀三酰胺胺络合物，可通过烷烃消除制得无载体的铀-键（参见方案）。 DFT分析显示了U-Re键中的σ和π组合，但the的贡献占主导，分子中的原子分析显示了闭合壳，主要是离子铀-相互作用。

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《Chemistry: A European journal》 |2011年第25期|共4页
作者
Gardner B.M.; McMaster J.; Moro F.; Lewis W.; Blake A.J.; Liddle S.T.;
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正文语种 eng
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alkane elimination; density functional calculations; metal-metal bonding; rhenium; uranium;

机译：烷烃消除密度泛函计算金属金属键;铀;

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1. An unsupported uranium-rhenium complex prepared by alkane elimination [J] . Gardner B.M., McMaster J., Moro F., Chemistry: A European journal . 2011,第25期

机译：通过消除烷烃制得的无载体铀-complex络合物
2. Synthesis and structure of [{N(CH_2CH_2NSiMe_3)_3}URe(η~5-C_5H_5)_2]: a heterobimetallic complex with an unsupported uranium-rhenium bond [J] . Benedict M. Gardner, Jonathan McMaster, William Lewis, Chemical Communications . 2009,第20期

机译：[{N（CH_2CH_2NSiMe_3）_3} URe（η〜5-C_5H_5）_2]的合成和结构：具有不支持的铀-键的杂双金属配合物
3. Unexpected Formation of NHC-Stabilized Hydrosilylyne Complexes via Alkane Elimination from NHC-Stabilized Hydrido(alkylsilylene) Complexes [J] . Tetsuya Fukuda, Hisako Hashimoto, Hiromi Tobita Journal of the American Chemical Society . 2015,第34期

机译：通过NHC稳定的氢（烷基亚甲硅烷基）络合物的烷烃消除，意外形成了NHC稳定的氢甲硅烷基络合物
4. Toward Eliminating An Unsupported Statement In Engineering Education Research And Literature [C] . Keith Holbert ASEE Annual Conference . 2009

机译：消除工程教育研究与文学中不受支持的陈述
5. Beta-hydrogen elimination from late transition metal alkoxide complexes, nitrogen-hydrogen bond forming reductive elimination, and nitrogen-hydrogen oxidative addition to late transition metal complexes. [D] . Zhao, Jing. 2005

机译：从后期过渡金属醇盐配合物中消除β-氢，形成氮-氢键形成还原性消除，以及向后期过渡金属配合物中进行氮-氢氧化。
6. Reconstitution of Plant Alkane Biosynthesis in Yeast Demonstrates That Arabidopsis ECERIFERUM1 and ECERIFERUM3 Are Core Components of a Very-Long-Chain Alkane Synthesis Complex [O] . Amélie Bernard, Frédéric Domergue, Stéphanie Pascal, 2012

机译：酵母中植物烷烃生物合成的重构表明拟南芥ECERIFERUM1和ECERIFERUM3是超长链烷烃合成复合物的核心成分
7. 1,8-Bis(silylamido)naphthalene complexes of magnesium and zinc synthesized through alkane elimination reactions [O] . Bradley, Mark, Birchall, Christopher, Blake, Alexander J., 2017

机译：通过烷烃消除反应合成的镁和锌的1,8-双（甲硅烷基）萘配合物
8. Mechanisms of Alkane Eliminations from the Intermediate Produced by Reactions of the Hydroxide and Methoxide Negative Ions with Tetramethylsilane in the Gas Phase [R] . Sheldon, J. C., Hayes, R. N., Bowie, J. H. 1987

机译：在气相中由氢氧化物和甲氧基负离子与四甲基硅烷反应产生的中间体烷烃消除机理

An unsupported uranium-rhenium complex prepared by alkane elimination

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