Catalytic C-H bond activation at nanoscale lewis acidic aluminium fluorides: H/D exchange reactions at aromatic and aliphatic hydrocarbons

Prechtl M.H.G.; Teltewskoi M.; Dimitrov A.; Kemnitz E.; Braun T.

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Catalytic C-H bond activation at nanoscale lewis acidic aluminium fluorides: H/D exchange reactions at aromatic and aliphatic hydrocarbons

机译：纳米级刘易斯酸性铝氟化物的催化C-H键活化：在芳烃和脂族烃上的H / D交换反应

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Nanoscopic amorphous Lewis acidic aluminium fluorides, such as aluminium chlorofluoride (ACF) and high-surface aluminium fluoride (HS-AlF_3), are capable of activating C-H bonds of aliphatic hydrocarbons. H/D exchange reactions are catalysed under mild conditions (40 °C).

机译：纳米级无定形路易斯酸性酸性铝氟化物，例如氯氟化铝（ACF）和高表面氟化铝（HS-AlF_3），能够活化脂肪烃的C-H键。 H / D交换反应在温和的条件下（40°C）进行催化。

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《Chemistry: A European journal》 |2011年第51期|共4页
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Prechtl M.H.G.; Teltewskoi M.; Dimitrov A.; Kemnitz E.; Braun T.;
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正文语种 eng
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aluminium fluorides; bifunctional catalysts; C-H activation; H/D exchange; Lewis acids;

机译：氟化铝;双功能催化剂;C-H活化;H / D交换;路易斯酸;

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1. Catalytic C-H bond activation at nanoscale lewis acidic aluminium fluorides: H/D exchange reactions at aromatic and aliphatic hydrocarbons [J] . Prechtl M.H.G., Teltewskoi M., Dimitrov A., Chemistry: A European journal . 2011,第51期

机译：纳米级刘易斯酸性铝氟化物的催化C-H键活化：在芳烃和脂族烃上的H / D交换反应
2. Metal ion-mediated selective activations of C-H and C-CI bonds. Direct aromatic thiolation reactions via C-S bond cleavage of dithioacids [J] . BIDYUT KUMAR SANTRA, GOUTAM KUMAR LAHIRI Proceedings of the Indian Academy of Sciences . 1999,第3期

机译：金属离子介导的C-H和C-CI键的选择性活化。通过二硫代酸的C-S键裂解直接进行芳族硫醇化反应
3. Stoichiometric C-H Bond Cleavage Reaction in a Bis(carboxylato)ruthenium(II) Complex and Its Application to the Catalytic H-D Exchange Reaction of Carboxylic Acids [J] . ChemCatChem . 2013,第5期

机译：化学计量的C-H键切割反应在双（羧基）钌（II）复合物中及其在羧酸催化H-D催化H-D交换反应中的应用
4. C-H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen-Deuterium Exchange and C-C Bond-Forming Reactions [C] . Steven R. Klei, Klan L. Tan, Jeffrey T. Golden, American Chemical Society National Meeting . 2004

机译：铱和铑配合物的C-H键活化：催化氢 - 氘交换和C-C键形成反应
5. Copper-Mediated Oxidative Decarboxylative Coupling Reactions: Trifluoromethylation of Heteroarene C-H bonds with Trifluoroacetic Acid as the CF3 Source and C-H Arylation of Benzoxazoles with Benzoic Acids [D] . Ju, Lin 2015

机译：铜介导的氧化脱羧偶联反应：以三氟乙酸为CF3源的杂芳烃C-H键的三氟甲基化和苯并恶唑与苯甲酸的C-H芳基化
6. Air/Water-Stable Tridentate NHC-PdII Complex; Catalytic C-H Activation of Hydrocarbons via H/D Exchange Process in D2O [O] . Joo Ho Lee, Kyung Soo Yoo, Chan Pil Park, -1

机译：空气/水稳定的三齿NHC-PdII复合物;在D2O中通过H / D交换过程催化碳氢活化碳氢化合物
7. Catalytic C-H Bond Activation at Nanoscale Lewis Acidic Aluminium Fluorides: H/D Exchange Reactions at Aromatic and Aliphatic Hydrocarbons [O] . Prechtl M. H. G., Teltewskoi M., Dimitrov A., 2011

机译：纳米级路易斯酸性铝氟化物的催化C-H键活化：在芳烃和脂肪烃上的H / D交换反应

Catalytic C-H bond activation at nanoscale lewis acidic aluminium fluorides: H/D exchange reactions at aromatic and aliphatic hydrocarbons

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