Gold(I)-catalyzed, highly diastereoselective, tandem heterocyclizations/ [3+2] cycloadditions: Synthesis of highly substituted cyclopenta[c]furans

Gao H.; Wu X.; Zhang J.

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Gold(I)-catalyzed, highly diastereoselective, tandem heterocyclizations/ [3+2] cycloadditions: Synthesis of highly substituted cyclopenta[c]furans

机译：金（I）催化的，高度非对映选择性的串联杂环化/ [3 + 2]环加成反应：高度取代的环戊[c]呋喃的合成

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摘要

The domino effect: A novel, cationic, gold(I)-catalyzed [3+2], tandem bicyclization, which provides rapid, efficient, and diastereoselective access to highly substituted cyclopenta[c]furans from simple, readily available 2-(1-alkynyl)-2-alken-1-ones and 3-styrylindoles under mild conditions, is described (see scheme).

机译：多米诺骨牌效应：一种新颖的，阳离子的，金（I）催化的[3 + 2]串联双环化，可快速，高效且非对映选择性地从简单易得的2-（1）取代高度取代的环戊[c]呋喃描述了在温和条件下的（-炔基）-2-烯烃-1-酮和3-苯乙烯基吲哚（参见方案）。

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《Chemistry: A European journal》 |2011年第10期|共4页
作者
Gao H.; Wu X.; Zhang J.;
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正文语种 eng
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cycloaddition; cyclopentacfurans; diastereoselectivity; domino reactions; gold;

机译：环加成;环戊并[c]呋喃;非对映选择性;多米诺反应;金;

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1. Gold(I)-Catalyzed, Highly Diastereoselective, Tandem Heterocyclizations/[3+2] Cycloadditions: Synthesis of Highly Substituted Cyclopenta[c]furans [J] . Hongyin Gao, Xingxing Wu, Prof. Dr. Junliang Zhang Chemistry - A European Journal . 2011,第10期

机译：金（I）催化，高非对映选择性，串联杂环/ [3 + 2]环加成：高度取代的环戊[c]呋喃的合成
2. Gold(I)-Catalyzed 1,2-Acyloxy Migration/[3+2] Cycloaddition of 1,6-Diynes with an Ynamide Propargyl Ester Moiety: Highly Efficient Synthesis of Functionalized Cyclopenta[b]indoles [J] . Liu Jun, Chen Ming, Zhang Liangwei, Chemistry: A European journal . 2015,第3期

机译：金（I）催化的1，6-二炔与亚酰胺丙炔基部分的1,2-酰氧基迁移/ [3 + 2]环加成反应：高效合成官能化的环戊[b]吲哚
3. Highly Substituted FuroACHTUNGTRENUNG[3,4-c]azepines by Gold(I)-Catalyzed Diastereoselective Tandem Double Heterocyclizations and 1,2-Alkyl Migration [J] . Hongyin Gao, Xiaoli Zhao, Yihua Yu, Chemistry: A European journal . 2010,第2期

机译：金（I）催化的非对映选择性串联双杂环和1，2-烷基的高度取代的FuroACHTUNGTRENUNG [3,4-c]氮杂
4. Highly Efficient Organic and Macromolecular Synthesis Using Sequential Copper Catalyzed Azide-Alkyne 3+2 Cycloaddition and ATRA/ATRP [C] . Carolynne L. Ricardo, Tomislav Pintauer American Chemical Society symposium on controlled/living radical polymerization . 2012

机译：连续铜催化叠氮化物-炔烃3 + 2环加成反应和ATRA / ATRP的高效有机和大分子合成
5. Development of highly diastereoselective FeCl3 catalyzed prins and Friedel-Crafts cyclization and investigation of highly substituted tetrahydropyrans via Cu(OTf)2-bisphosphine olefin migration-prins cyclization. [D] . Keyes, Chad A. 2014

机译：高度非对映选择性的FeCl3催化蛋白的开发和Friedel-Crafts环化，以及通过Cu（OTf）2-双膦烯烃迁移-蛋白环化对高度取代的四氢吡喃的研究。
6. Highly-Substituted Enantioenriched Cyclopentane Derivatives by Palladium-Catalyzed 3+2 Trimethylenemethane Cycloadditions with Disubstituted Nitroalkenes [O] . Barry M. Trost, Dustin A. Bringley, B. Michael OKeefe -1

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7. Two-Step Formal 3+2 Cycloaddition of Enones/Enals and Allenyl MOM Ether: Gold-Catalyzed Highly Diastereoselective Synthesis of Cyclopentanone Enol Ether Containing an All-Carbon Quaternary Center [O] . -1

机译：两步正式3 + 2环加成蜗牛/烯酮和亚环烯醚：金催化的高度自映选择性合成含有全碳四元中心的环戊酮烯醇醚

Gold(I)-catalyzed, highly diastereoselective, tandem heterocyclizations/ [3+2] cycloadditions: Synthesis of highly substituted cyclopenta[c]furans

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