Gold(I)-catalyzed tandem oxidative ring-opening/C-C bond cleavage reactions of vinylidenecyclopropanes with secondary amines under an oxygen atmosphere

Lu B.-L.; Shi M.

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Gold(I)-catalyzed tandem oxidative ring-opening/C-C bond cleavage reactions of vinylidenecyclopropanes with secondary amines under an oxygen atmosphere

机译：氧气氛下亚乙烯基环丙烷与仲胺的金（I）催化串联氧化开环/ C-C键裂解反应

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A Midas touch! Gold(I)-catalyzed tandem oxidative ring-opening/C-C bond cleavage reactions of vinylidenecyclopropanes with a variety of secondary amines proceeded smoothly in toluene or 1,1,2,2-tetrachloroethane (TCE) to give the corresponding amides in moderate to good yields under oxygen atmosphere (see scheme; DCE=1,2-dichloroethane). The scope and limitations as well as the plausible mechanisms have been discussed.

机译：点石成金！亚乙烯基亚环丙烷与多种仲胺的金（I）催化串联氧化性开环/ CC键裂解反应在甲苯或1,1,2,2-四氯乙烷（TCE）中顺利进行，得到中等至良好的相应酰胺在氧气气氛下收率（参见方案; DCE ＝ 1，2-二氯乙烷）。已经讨论了范围和局限性以及合理的机制。

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《Chemistry: A European journal》 |2011年第33期|共6页
作者
Lu B.-L.; Shi M.;
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正文语种 eng
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amides; amines; gold; oxidative C-C bond cleavage; ring-opening; vinylidenecyclopropanes;

机译：酰胺;胺;金;氧化性C-C键断裂;开环;亚乙烯基环丙烷;

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1. Gold(I)-catalyzed tandem oxidative ring-opening/C-C bond cleavage reactions of vinylidenecyclopropanes with secondary amines under an oxygen atmosphere [J] . Lu B.-L., Shi M. Chemistry: A European journal . 2011,第33期

机译：氧气氛下亚乙烯基环丙烷与仲胺的金（I）催化串联氧化开环/ C-C键裂解反应
2. Gold(I)-Catalyzed Intramolecular Carbon-Oxygen Bond Cleavage Reaction via Gold Carbenes Derived from Vinylidenecyclopropanes [J] . Li De-Yao, Wei Yin, Shi Min Advanced synthesis & catalysis . 2016,第19期

机译：金（I）催化衍生的通过亚乙烯基亚环丙烷衍生的金苯甲酸酯进行的分子内碳氧键裂解反应。
3. Palladium-Catalyzed Oxidative Alkynylation of Alkenes via C-C Bond Cleavage under Oxygen Atmosphere [J] . Takahiro Nishimura, Hitoshi Araki, Yasunari Maeda, Organic letters . 2003,第17期

机译：氧气氛下C-C键裂解对钯催化的烯烃氧化烯丙基化反应
4. A Ruthenium-Catalyzed Reaction of Aromatic Ketones with Organoboronic Acid Esters:A New Method for C-C Bond Formation via C-H Bonds Cleavage [C] . Fumitoshi Kakiuchi, Shintaro Kan, Kimitaka Igi, Symposium on Organometallic Chemistry . 2003

机译：芳香酮与有机硼酸酯的芳香酮催化反应：通过C-H键切割的C-C键形成新方法
5. Bulk gold catalyzed oxidation reactions of amines and isocyanides and iron porphyrin catalyzed N-H and O-H bond insertion/cyclization reactions of diamines and aminoalcohols [D] . Klobukowski, Erik Richard 2011

机译：胺和异氰化物的体金催化氧化反应和铁卟啉催化的二胺和氨基醇的N-H和O-H键插入/环化反应
6. Iridium-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes with secondary amine nucleophiles [O] . Dingqiao Yang, Ping Hu, Yuhua Long, 2009

机译：铱催化氧杂双环烯烃与仲胺亲核试剂的不对称开环反应
7. Cleavage of a Carbon-Carbon Triple Bond via Gold-Catalyzed Cascade Cyclization/Oxidative Cleavage Reactions of (Z)-Enynols with Molecular Oxygen [O] . -1

机译：通过金催化的级联环化/氧化裂解反应（Z） - 烯醇的分子氧裂解碳 - 碳三键的切割
8. Redox Catalysis Involving Substrate Photooxidation with Catalyst Regeneration bySubstrate Reduction. Simultaneous Oxidative C-H Bond Cleavage and Reductive C-S Bond Cleavage in Thioethers Catalyzed by W10O324- [R] . Chambers, R. C., Hill, C. L. 1990

机译：氧化还原催化与底物光氧化反应的催化剂再生通过底物还原。 W10O324催化的硫醚同时氧化C-H键断裂和还原C-s键断裂

Gold(I)-catalyzed tandem oxidative ring-opening/C-C bond cleavage reactions of vinylidenecyclopropanes with secondary amines under an oxygen atmosphere

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