Highly enantioselective reduction of β-amino nitroolefins with a simple n-sulfinyl urea as bifunctional catalyst

Liu X.-W.; Yan Y.; Wang Y.-Q.; Wang C.; Sun J.

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Highly enantioselective reduction of β-amino nitroolefins with a simple n-sulfinyl urea as bifunctional catalyst

机译：以简单的亚磺酰基脲为双官能催化剂，高度对映选择性还原β-氨基硝基烯烃

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Simple but effective: A structurally simple N-sulfinyl urea was found to be a highly efficient bifunctional catalyst, which allows for the development of a novel pathway for the construction of chiral β-amino nitroalkanes through enantioselective reduction of β-amino nitroolefins by trichlorosilane. High yields and excellent enantioselectivities were obtained for a broad range of β-arylamino nitroolefin substrates (see scheme).

机译：简单但有效：发现结构简单的N-亚磺酰基尿素是一种高效的双功能催化剂，它允许通过三氯硅烷对映体选择性还原β-氨基硝基烯烃来开发构建手性β-氨基硝基烷烃的新途径。对于宽范围的β-芳基氨基硝基烯烃底物，均获得了高收率和出色的对映选择性（参见方案）。

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《Chemistry: A European journal》 |2012年第30期|共4页
作者
Liu X.-W.; Yan Y.; Wang Y.-Q.; Wang C.; Sun J.;
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正文语种 eng
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amino nitroolefins; asymmetric catalysis; bifunctional catalyst; hydrosilylation; reduction; sulfinyl ureas;

机译：氨基硝基烯烃不对称催化双功能催化剂氢化硅烷化还原亚磺酰基脲;

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1. Highly enantioselective reduction of β-amino nitroolefins with a simple n-sulfinyl urea as bifunctional catalyst [J] . Liu X.-W., Yan Y., Wang Y.-Q., Chemistry: A European journal . 2012,第30期

机译：以简单的亚磺酰基脲为双官能催化剂，高度对映选择性还原β-氨基硝基烯烃
2. Highly Enantioselective Michael Addition of Aromatic Ketones to Nitroolefins Promoted by Chiral Bifunctional Primary Amine-thiourea Catalysts Based on Saccharides [J] . Kun Liu, Han-Feng Cui, Jing Nie, Organic letters . 2007,第5期

机译：基于糖类的手性双功能伯胺-硫脲催化剂促进的硝基酮对硝基烯烃的高对映选择性迈克尔加成反应
3. Novel and highly efficient bifunctional calixarene thiourea derivatives as organocatalysts for enantioselective Michael reaction of nitroolefins with diketones [J] . Genc Hayriye Nevin, Sirit Abdulkadir Journal of Inclusion Phenomena and Macrocyclic Chemistry . 2018,第1a2期

机译：新颖且高效的双官能钙芳烃硫脲衍生物作为硝烯烃与二酮映射的映射性迈克尔反应的有机催化剂
4. Sugar Based g-Amino Alcohol Organocatalyst for Enantioselective Michael Addition of β-Keto Esters with Nitroolefins [C] . Divakar Ganesan, Chigusa Seki, Koji Uwai 日本化学会春季年会講演予稿集 . 2018

机译：糖基G-氨基酒精有机催化剂用于对映选择性的迈克尔加入亚硝烯烃的β-酮酯
5. Enantioselective Synthesis of β-Amino Acid Derivatives Using Amidine-Based and Bifunctional Organocatalysts [D] . Straub, Matthew Robert. 2021

机译：使用脒基和双官能有机催化剂对β-氨基酸衍生物的对映选择性合成
6. Enantioselective Organocatalytic Reduction of Ketones using Bifunctional Thiourea-Amine Catalysts [O] . De Run Li, Anyu He, J. R. Falck -1

机译：对映选择性酮的有机催化还原使用双功能硫脲胺催化剂
7. Highly Enantioselective Michael Addition of Aromatic Ketones to Nitroolefins Promoted by Chiral Bifunctional Primary Amine-thiourea Catalysts Based on Saccharides [O] . -1

机译：高映选择性迈克尔在基于糖类的手性双官能初级胺 - 硫脲催化剂促进的亚罗烯烃添加芳香酮

Highly enantioselective reduction of β-amino nitroolefins with a simple n-sulfinyl urea as bifunctional catalyst

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