Sequestering aromatic molecules with a spin-crossover Fe ~(II) microporous coordination polymer

Mu?oz-Lara F.J.; Gaspar A.B.; Mu?oz M.C.; Arai M.; Kitagawa S.; Ohba M.; Real J.A.

首页> 外文期刊>Chemistry: A European journal >Sequestering aromatic molecules with a spin-crossover Fe ~(II) microporous coordination polymer

【24h】

Sequestering aromatic molecules with a spin-crossover Fe ~(II) microporous coordination polymer

机译：用自旋交联的Fe〜（II）微孔配位聚合物螯合芳族分子

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A novel Hoffman-like tri-dimensional coordination polymer {Fe(dpe)[Pt(CN) _4]}.0.5(dpe) based on the organic pillar ligand 1,2-di(4-pyridyl)ethylene (dpe; trans isomer), which exhibits spin crossover and porous properties was reported. Detection of the guest molecules was performed by analyzing the temperature dependence of the magnetic susceptibility of the corresponding clathrate. Single crystals of {Fe(dpe)[Pt(CN) _4]}.0.5(dpe) were grown by means of a slow diffusion technique. (NH _4) _2Fe(SO _4) _2.6H _2O dissolved in water was placed in one side of a multiarm-shaped vessel. The other arms contained a solution of dpe in methanol and a solution of K _2Pt(CN) _4.3H _2O in water. Square-shaped orange crystals of {Fe(dpe)[Pt(CN) _4]}.0.5(dpe) suitable for single crystal X-ray analysis were obtained after three weeks. Finger-print like magnetic response pattern to each analyte was attained.

机译：基于有机支柱配体1,2-二（4-吡啶基）乙烯（dpe;反式异构体）的新型霍夫曼样三维配位聚合物{Fe（dpe）[Pt（CN）_4]}。0.5（dpe）），表现出自旋交叉和多孔性质。通过分析相应包合物的磁化率的温度依赖性来进行客体分子的检测。 {Fe（dpe）[Pt（CN）_4] .0.5（dpe）的单晶通过慢扩散技术生长。将溶解在水中的（NH _4）_2Fe（SO _4）_2.6H _2O放在多臂形容器的一侧。其他臂包含在甲醇中的dpe溶液和在水中的K _2Pt（CN）_4.3H _2O溶液。三周后，获得了适用于单晶X射线分析的{Fe（dpe）[Pt（CN）_4]}。0.5（dpe）的方形橙色晶体。获得了对每种分析物的指纹状磁响应模式。

著录项

来源
《Chemistry: A European journal》 |2012年第26期|共6页
作者
Mu?oz-Lara F.J.; Gaspar A.B.; Mu?oz M.C.; Arai M.; Kitagawa S.; Ohba M.; Real J.A.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
iron; magnetic properties; phase transition absorption; porous coordination polymers; spin crossover;

机译：铁;磁性;相变吸收;多孔配位聚合物;自旋交;

相似文献

外文文献
中文文献
专利

1. Sequestering aromatic molecules with a spin-crossover Fe ~(II) microporous coordination polymer [J] . Mu?oz-Lara F.J., Gaspar A.B., Mu?oz M.C., Chemistry: A European journal . 2012,第26期

机译：用自旋交联的Fe〜（II）微孔配位聚合物螯合芳族分子
2. Novel Iron(II) Microporous Spin-Crossover Coordination Polymers with Enhanced Pore Size [J] . Francisco J. Muñoz-Lara, † Ana B. Gaspar, † M. Carmen Muñoz, Inorganic Chemistry . 2013,第1期

机译：孔径增大的新型铁（II）微孔自旋交配聚合物
3. Novel iron(II) microporous spin-crossover coordination polymers with enhanced pore size [J] . Mu?oz-Lara F.J., Gaspar A.B., Mu?oz M.C., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2013,第1期

机译：孔径增大的新型铁（II）微孔自旋交联配位聚合物
4. (07D101) Geometric structure, electronic structure, and spin transition of several Fe~(II) spin-crossover molecules [C] . Nguyen Anh Tuan Annual Conference on Magnetism and Magnetic Materials . 2012

机译：（07D101）几何结构，电子结构和旋转过渡几种Fe〜（ii）旋转分子
5. I. Effect of an anionic polymer on the separation of cationic molecules by capillary electrophoresis. II. Off-line and on-line photochemical reaction of aromatic nitro compounds with detection by molecular spectroscopy and mass spectrometry. [D] . Musial, Beata Anna. 2002

机译：I.阴离子聚合物对通过毛细管电泳分离阳离子分子的影响。二。芳香族硝基化合物的离线和在线光化学反应，并通过分子光谱和质谱检测。
6. Crystal Engineering of Schiff Base Zn(II) and Cd(II) Homo- and Zn(II)M(II) (M = Mn or Cd) Heterometallic Coordination Polymers and Their Ability to Accommodate Solvent Guest Molecules [O] . Olga Danilescu, Paulina N. Bourosh, Oleg Petuhov, 2021

机译：Schiff基Zn（II）和CD（II）型和Zn（II）M（II）（M = Mn或Cd）杂动属配位聚合物及其容纳溶剂客体分子的能力
7. Cover Feature: Cyanido-Bridged FeII -MI Dimetallic Hofmann-Like Spin-Crossover Coordination Polymers Based on 2,6-Naphthyridine (Eur. J. Inorg. Chem. 3-4/2018) [O] . Lucía Piñeiro-López, Francisco Javier Valverde-Muñoz, Maksym Seredyuk, 2018

机译：封面特点：基于2,6-萘吡啶的Cyanido-Bridged Feii-Mi Dimetallic Hofmann样旋转协调聚合物（EUR。J. Inorg。化学。3-4 / 2018）
8. Transfer Pd(0) Catalyzed Polymerization Reactions. III. Polymerization by Cross-Coupling of Alkyl-Boron Compounds and Aromatic Halides Catalyzed by PdCl2 (dppf) and Bases [R] . Cramer, E., Percec, V. 1990

机译：转移pd（0）催化的聚合反应。 III。 pdCl2（dppf）和碱催化的烷基硼化合物与芳香卤化物的交叉偶联聚合

Sequestering aromatic molecules with a spin-crossover Fe ~(II) microporous coordination polymer

摘要

著录项

相似文献

相关主题

期刊订阅