Cyclic thiouronium ionic liquids: Physicochemical properties and their electronic structure probed by X-ray induced photoelectron spectroscopy

Taccardi N.; Niedermaier I.; Maier F.; Steinrück H.-P.; Wasserscheid P.

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Cyclic thiouronium ionic liquids: Physicochemical properties and their electronic structure probed by X-ray induced photoelectron spectroscopy

机译：环状硫脲鎓离子液体：X射线诱导的光电子能谱探测的理化性质及其电子结构

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Radiography of a structure skeleton: Cyclic thiouronium ionic liquids have been synthesized and characterized in such a way that the straightforward introduction of three different alkyl substituents at the cation has been realized. X-ray induced photoelectron spectroscopy studies indicated a significant electronic contribution of the free electrons at the sulfur to stabilize the cationic charge, leading to structures with peculiar physicochemical properties (see figure).

机译：结构骨架的放射线照相：合成并表征了环状硫脲鎓离子液体，使得可以在阳离子上直接引入三个不同的烷基取代基。 X射线诱导的光电子能谱研究表明，硫上的自由电子对稳定阳离子电荷具有重要的电子贡献，从而导致结构具有独特的理化特性（见图）。

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《Chemistry: A European journal》 |2012年第27期|共4页
作者
Taccardi N.; Niedermaier I.; Maier F.; Steinrück H.-P.; Wasserscheid P.;
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正文语种 eng
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关键词
cyclic thiouronium; electronic structure; ionic liquids; thiones; X-ray photoelectron spectroscopy;

机译：环状硫脲;电子结构;离子液体;硫酮;X射线光电子能谱;

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1. Cyclic thiouronium ionic liquids: Physicochemical properties and their electronic structure probed by X-ray induced photoelectron spectroscopy [J] . Taccardi N., Niedermaier I., Maier F., Chemistry: A European journal . 2012,第27期

机译：环状硫脲鎓离子液体：X射线诱导的光电子能谱探测的理化性质及其电子结构
2. Towards a Molecular Understanding of Cation–Anion Interactions—Probing the Electronic Structure of Imidazolium Ionic Liquids by NMR Spectroscopy, X-ray Photoelectron Spectroscopy and Theoretical Calculations [J] . Till Cremer, Claudia Kolbeck, Kevin R. J. Lovelock Dr., Chemistry - A European Journal . 2010,第30期

机译：对阳离子与阴离子相互作用的分子理解-咪唑鎓离子液体的电子结构通过NMR光谱，X射线光电子能谱和理论计算
3. Cover Picture: Towards a Molecular Understanding of Cation–Anion Interactions—Probing the Electronic Structure of Imidazolium Ionic Liquids by NMR Spectroscopy, X-ray Photoelectron Spectroscopy and Theoretical Calculations (Chem. Eur. J. 30/2010) [J] . Till Cremer, Claudia Kolbeck, Kevin R. J. Lovelock Dr., Chemistry - A European Journal . 2010,第30期

机译：封面图片：对阳离子与阴离子相互作用的分子理解—咪唑鎓离子液体的电子结构，通过NMR光谱，X射线光电子能谱和理论计算进行探究（Chem。Eur。J. 30/2010）
4. Investigation of the Electronic Properties of the ZrO_2 and HfO_2 Thin Films by Scanning Probe Microscopy and X-ray Photoelectron Spectroscopy [C] . D.A. Antonov, D.O. Filatov, G.A. Maximov, Nano Science and Technology Institute(NSTI) Nanotechnology Conference and Trade Show(NSTI Nanotech 2006) vol.1 . 2006

机译：ZrO_2和HfO_2薄膜的电子性质的扫描探针显微镜和X射线光电子能谱研究
5. Interfacial Chemistry of Water at the Ionic Liquid - Vapor Interface Probed by Ambient Pressure X-ray Photoelectron Spectroscopy [D] . Broderick, Alicia M. 2018

机译：环境压力X射线光电子能谱探测离子液体-蒸汽界面上水的界面化学
6. Annealing induced atomic rearrangements on (GaIn) (NAs) probed by hard X-ray photoelectron spectroscopy and X-ray absorption fine structure [O] . Fumitaro Ishikawa, Kotaro Higashi, Satoshi Fuyuno, -1

机译：硬X射线光电子能谱和X射线吸收精细结构探测的（GaIn）（NAs）上的退火诱导的原子重排
7. Cover Picture: Towards a Molecular Understanding of Cation-Anion Interactions-Probing the Electronic Structure of Imidazolium Ionic Liquids by NMR Spectroscopy, X-ray Photoelectron Spectroscopy and Theoretical Calculations (Chem. Eur. J. 30/2010) [O] . Till Cremer, Claudia Kolbeck, Kevin R. J. Lovelock, 2010

机译：覆盖图片：朝向阳离子相互作用的分子理解通过NMR光谱，X射线光电子能谱和理论计算探测咪唑鎓离子液体的电子结构（Chem.Eur。J.30/2010）
8. Single-State ELectronic Structure Measurements Using Time-Resolved X-Ray Laser Induced Photoelectron Spectroscopy [R] . Nelson, A. J., Dunn, J., van Buuren, T., 2004

机译：使用时间分辨X射线激光诱导光电子能谱的单态ELectronic结构测量

Cyclic thiouronium ionic liquids: Physicochemical properties and their electronic structure probed by X-ray induced photoelectron spectroscopy

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