An efficient mixed-ligand Pd catalytic system to promote C-N coupling for the synthesis of N-arylaminotriazole nucleosides

Fan Y.; Xia Y.; Tang J.; Ziarelli F.; Qu F.; Rocchi P.; Iovanna J.L.; Peng L.

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An efficient mixed-ligand Pd catalytic system to promote C-N coupling for the synthesis of N-arylaminotriazole nucleosides

机译：一个有效的混合配体钯催化体系，促进C-N偶联，用于合成N-芳基氨基三唑核苷

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Make it unique! A mixed-ligand system of Pd/Synphos/Xantphos promotes effective C-N coupling in the synthesis of various N-arylaminotriazole and N-arylaminopurine nucleoside analogues. This catalytic system is strikingly powerful and efficient, allowing for unparalleled substrate scope and high product yields as well as promotion of C-Cl bond activation for C-N coupling (see scheme).

机译：使其独一无二！ Pd / Synphos / Xantphos的混合配体系统可在合成各种N-芳基氨基三唑和N-芳基氨基嘌呤核苷类似物时促进有效的C-N偶联。该催化系统具有强大的功能和效率，可实现无与伦比的底物范围和高产品收率，并促进C-N键偶联的C-Cl键活化（参见方案）。

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《Chemistry: A European journal》 |2012年第8期|共5页
作者
Fan Y.; Xia Y.; Tang J.; Ziarelli F.; Qu F.; Rocchi P.; Iovanna J.L.; Peng L.;
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antitumor agents; arylamination; cross-coupling; nucleosides; palladium;

机译：抗肿瘤药芳基化交叉偶联核苷钯;

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专利

1. An efficient mixed-ligand Pd catalytic system to promote C-N coupling for the synthesis of N-arylaminotriazole nucleosides [J] . Fan Y., Xia Y., Tang J., Chemistry: A European journal . 2012,第8期

机译：一个有效的混合配体钯催化体系，促进C-N偶联，用于合成N-芳基氨基三唑核苷
2. Synthesis and characterization of MCM-41-Biurea-Pd as a heterogeneous nanocatalyst and using its catalytic efficacy in C-C, C-N and C-O coupling reactions [J] . Batmani Hana, Pesyan Nader Noroozi, Havasi Forugh Applied Organometallic Chemistry . 2018,第8期

机译：MCM-41-Biurea-Pd作为异质纳米催化剂的合成与表征，并在C-C，C-N和C-O偶联反应中使用其催化疗效
3. Heteroleptic (N-heterocyclic carbene)-Pd-pyrazole (indazole) complexes: Synthesis, characterization and catalytic activities towards C-C and C-N cross-coupling reactions [J] . Yang Jin Applied Organometallic Chemistry . 2017,第10期

机译：异致（N-杂环碳烯）-PD-吡唑（吲唑）配合物：合成，表征和致催化活性为C-C和C-N交叉偶联反应
4. Aqueous Phase Sonogashira Cross-Coupling Reaction in Synthesis of Bile Acid Conjugates of Purine and Pyrimidine Nucleosides and Nucleoside Triphosphates; Towards Bile Acid -Functionalized Nucleic Acids [C] . Satu Ikonen, Radek Pohl, Michal Hocek European Symposium on Organic Chemistry . 2009

机译：水相Sonogashira交叉偶联反应在嘌呤和嘧啶核苷的合成中合成，嘧啶核苷和核苷三磷酸盐;朝向胆汁酸 - 官能化核酸
5. Synthesis of multisubstituted halo -olefins via Pd-catalyzed cross -coupling reactions. Applications in nucleoside chemistry [D] . Andrei, Daniela 2006

机译：通过Pd催化的交叉偶联反应合成多取代的卤代烯烃。在核苷化学中的应用
6. Photo-Assisted Synthesis of a Pd–Ag@CQD Nanohybridand Its Catalytic Efficiency in Promoting the Suzuki–MiyauraCross-Coupling Reaction under Ligand-Free and Ambient Conditions [O] . Rajarshi Bayan, Niranjan Karak, * 2017

机译：Pd–Ag @ CQD纳米杂化物的光辅助合成及其催化铃木宫浦的催化效率无配体和环境条件下的交叉偶联反应
7. Photo-Assisted Synthesis of a Pd–Ag@CQD Nanohybrid and Its Catalytic Efficiency in Promoting the Suzuki–Miyaura Cross-Coupling Reaction under Ligand-Free and Ambient Conditions [O] . Rajarshi Bayan, Niranjan Karak 2017

机译：光谱辅助合成pd-ag @ CQD纳米混合物及其在无配体和环境条件下促进suzuki-miyaura交叉偶联反应的催化效率

An efficient mixed-ligand Pd catalytic system to promote C-N coupling for the synthesis of N-arylaminotriazole nucleosides

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