Catalytic and enantioselective α-functionalization of oxindoles through oxidative reactions with naphthoquinones

Siau W.-Y.; Li W.; Xue F.; Ren Q.; Wu M.; Sun S.; Guo H.; Jiang X.; Wang J.

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Catalytic and enantioselective α-functionalization of oxindoles through oxidative reactions with naphthoquinones

机译：通过与萘醌的氧化反应催化和对映选择性α-官能化的吲哚

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Strong as an oxindole: The enantioselective assembly of 3,3-disubstituted oxindoles is an attractive and valuable target because of the unique properties of the oxindole core. A new organocatalyzed and enantioselective aerobic oxidative strategy for the assembly of this core structure from oxindoles and simple naphthoquinones is reported (see scheme).

机译：作为羟吲哚强：由于羟吲哚核的独特性质，3,3-二取代羟吲哚的对映选择性组装物是有吸引力且有价值的目标。报道了一种新的有机催化和对映体选择性好氧氧化策略，用于由氧吲哚和简单的萘醌组装该核心结构（参见方案）。

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《Chemistry: A European journal》 |2012年第31期|共5页
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Siau W.-Y.; Li W.; Xue F.; Ren Q.; Wu M.; Sun S.; Guo H.; Jiang X.; Wang J.;
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正文语种 eng
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asymmetric catalysis; indane; organocatalysis; oxindole; thiourea;

机译：不对称催化茚满有机催化吲哚硫脲;

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专利

1. Catalytic and enantioselective α-functionalization of oxindoles through oxidative reactions with naphthoquinones [J] . Siau W.-Y., Li W., Xue F., Chemistry: A European journal . 2012,第31期

机译：通过与萘醌的氧化反应催化和对映选择性α-官能化的吲哚
2. Catalytic and enantioselective α-functionalization of oxindoles through oxidative reactions with naphthoquinones [J] . Siau W.-Y., Li W., Xue F., Chemistry: A European journal . 2012,第31期

机译：通过与萘醌的氧化反应催化和对映选择性α-官能化的吲哚
3. Synthesis of 1,2-difunctionalized fine chemicals through catalytic, enantioselective ring-opening reactions of epoxides [J] . Schneider C Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2006,第23期

机译：通过环氧化物的催化，对映选择性开环反应合成1,2-双官能化精细化学品
4. Highly Efficient Synthesis of Oxindole Derivatives via Catalytic Intramolecular C-H Insertion Reactions of Diazoamides [C] . Nga Phan-Thi-Thanh, Masaya Tone, Hayato lnoue International Conference on Science and Technology . 2020

机译：通过催化分子内C-H插入式重氮酰胺的催化分子内C-H插入反应高效合成氧吲哚衍生物
5. Catalytic enantioselective synthesis of aryl substituted 3-hydroxy-2-oxindoles and 3,3-disubstituted-2-oxindoles. [D] . Sahin, Aziza Hatice. 2010

机译：芳基取代的3-羟基-2-氧吲哚和3,3-二取代的-2-氧吲哚的催化对映选择性合成。
6. Synthesis of chiral 3-substituted 3-amino-2-oxindoles through enantioselective catalytic nucleophilic additions to isatin imines [O] . Hélène Pellissier 2018

机译：通过对映异构亚胺的对映选择性催化亲核加成反应合成手性3-取代的3-氨基-2-氧吲哚
7. Catalytic Enantioselective Syntheses of Functionalized 3,3-Spirocyclopropyl Oxindoles and Vinylcyclopropanes via Ammonium Ylides Generated from α-Bromoketones [O] . Jinghua Luo, Weisheng Geng, Shixuan Cao, 2020

机译：通过α-溴化酮产生的氨基酯，催化致力化合成官能化的3,3-螺丙基氧胆碱和乙烯基环丙烷

Catalytic and enantioselective α-functionalization of oxindoles through oxidative reactions with naphthoquinones

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