Synthesis and Characterization of Various Photosensitive Copper(II) Complexes with 5-(1-Methylhydrazinyl)-1H-tetrazole as Ligand and Perchlorate, Nitrate, Dinitramide, and Chloride as Anions

Manuel Joas; Thomas M. Klap?tke; J?rg Stierstorfer; Norbert Szimhardt

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Synthesis and Characterization of Various Photosensitive Copper(II) Complexes with 5-(1-Methylhydrazinyl)-1H-tetrazole as Ligand and Perchlorate, Nitrate, Dinitramide, and Chloride as Anions

机译：以5-（1-甲基肼基）-1H-四唑为配体和高氯酸根，硝酸根，二酰胺和氯离子为阴离子的各种光敏铜（II）配合物的合成与表征

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The preparation of 5-(1- methylhydrazinyl)-1H-tetrazole monohydrate (1·H_2O) and various copper(II) complexes with perchlorate (2 and 3), nitrate (4, 5, and 6), dinitramide (7), and chloride (8) is described. The coordination compounds (monomers, dimers, and polymers) were characterized through infrared spectroscopy and elemental analysis. Further, the structures of 2 and 4-8 were determined by single-crystal X-ray diffraction. Compound 1 can act as a bidentate ligand in its neutral form (HMHT) and as a μ_2- or μ_3-bridging ligand in its deprotonated form (MHT). The energetic properties of the synthesized complexes, such as their sensitivities toward impact and friction, were determined, and laser ignition tests were performed. New information about the laser initiation process and the role of the anion in the initiation criterion was obtained. The perchlorate complexes 2 (T_(decomp)= 217 ℃) and 3 (T_(decomp)=206 ℃) are potential primary explosives.

机译：制备5-（1-甲基肼基）-1H-四唑一水合物（1·H_2O）和各种铜（II）与高氯酸盐（2和3），硝酸盐（4、5和6），二硝酰胺（7）的配合物，描述了氯化物（8）。通过红外光谱和元素分析表征了配位化合物（单体，二聚体和聚合物）。此外，通过单晶X射线衍射确定2和4-8的结构。化合物1可以以其中性形式（HMHT）充当双齿配体并且以其去质子化形式（MHT）充当μ_2-或μ_3-桥联配体。确定了合成配合物的能量性质，例如它们对冲击和摩擦的敏感性，并进行了激光点火试验。获得了有关激光引发过程以及阴离子在引发标准中的作用的新信息。高氯酸盐配合物2（T_（decomp）= 217℃）和3（T_（decomp）= 206℃）是潜在的主要爆炸物。

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《Chemistry: A European journal》 |2013年第30期|共9页
作者
Manuel Joas; Thomas M. Klap?tke; J?rg Stierstorfer; Norbert Szimhardt;
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coordination polymers; copper; energetic materials; laser initiation; ligand effects; primary explosives;

机译：配位聚合物;铜;高能材料;激光引发;配体效应;主炸药;

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3. Photosensitive Metal(II) Perchlorates with 1,2-Bis[5-(1- methylhydrazinyl)tetrazol-1-yl]ethane as Ligand: Synthesis, Characterization and Laser Ignition [J] . Manuel Joas, Thomas M. Klap?tke, Norbert Szimhardt European journal of inorganic chemistry . 2014,第3期

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Synthesis and Characterization of Various Photosensitive Copper(II) Complexes with 5-(1-Methylhydrazinyl)-1H-tetrazole as Ligand and Perchlorate, Nitrate, Dinitramide, and Chloride as Anions

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