Mechanism of the methyltrioxorhenium-catalyzed deoxydehydration of polyols: A new pathway revealed

Qu S.; Dang Y.; Wen M.; Wang Z.-X.

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Mechanism of the methyltrioxorhenium-catalyzed deoxydehydration of polyols: A new pathway revealed

机译：甲基三氧or催化多元醇脱氧的机理：揭示新途径

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Polyols pathway probed: Density functional theory computations reveal that the methyltrioxorhenium-catalyzed deoxydehydration of polyols follows pathway C, which is energetically more favorable than the previously proposed pathways A and B (see scheme). In addition to serving as solvent/reductant, the alcohol also acts as a shuttle to greatly facilitate various hydrogen-transfer steps.

机译：探查多元醇途径：密度泛函理论计算表明，甲基三氧or催化的多元醇脱氧脱水遵循途径C，在能量上比先前提出的途径A和B更有利（请参阅方案）。除了用作溶剂/还原剂外，醇还充当梭子，极大地促进了各种氢转移步骤。

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《Chemistry: A European journal》 |2013年第12期|共6页
作者
Qu S.; Dang Y.; Wen M.; Wang Z.-X.;
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正文语种 eng
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biomass; density functional calculations; deoxydehydration; hydrogen transfer; reaction mechanisms;

机译：生物质密度泛函计算脱氧脱水氢转移反应机理;

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1. Mechanism of the methyltrioxorhenium-catalyzed deoxydehydration of polyols: A new pathway revealed [J] . Qu S., Dang Y., Wen M., Chemistry: A European journal . 2013,第12期

机译：甲基三氧or催化多元醇脱氧的机理：揭示新途径
2. Hyperglycemia impairs acetylcholine-induced vasodilation of retinal arterioles through polyol pathway-independent mechanisms in rats [J] . MoriA., SaigoO., SakamotoK., Journal of pharmacological sciences. . 2010,第3期

机译：高血糖通过不依赖多元醇途径的机制损害乙酰胆碱诱导的视网膜小动脉血管舒张
3. Hyperglycemia Impairs Acetylcholine-Induced Vasodilation of Retinal Arterioles Through Polyol Pathway–Independent Mechanisms in Rats [J] . Asami Mori, Kenji Sakamoto, Kunio Ishii, Journal of pharmacological sciences. . 2010,第3期

机译：高血糖通过大鼠多元醇途径独立机制损害乙酰胆碱诱导的视网膜小动脉血管舒张。
4. NATIVE MASS SPECTROMETRY REVEAL FUNCTIONING MECHANISM OF MEMBRANE PROTEIN TRANSLOCATION PATHWAY [C] . Shahid Mehmood, Melanie McDowell, Irmgard Sinning, International Mass Spectrometry Conference . 2018

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5. The Involvement of Polyol Pathway in Hypgerglycemia and Cadmium Toxicity in the Establishment of Diabetic Neprhopathy [D] . Davis, Bethany Anne. 2018

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6. Metabolomic Analysis Reveals Vitamin D-induced Decrease in Polyol Pathway and Subtle Modulation of Glycolysis in HEK293T Cells [O] . G. C. Santos, J. D. Zeidler, J. A. Pérez-Valencia, -1

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7. Interactions between essential fatty acid, prostanoid, polyol pathway and nitric oxide mechanisms in the neurovascular deficit of diabetic rats [O] . N. E. Cameron, M. A. Cotter, T. C. Hohman 1996

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Mechanism of the methyltrioxorhenium-catalyzed deoxydehydration of polyols: A new pathway revealed

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