Enantioselective aza-Morita-Baylis-Hillman reaction with ketimines and acrolein catalyzed by organic assemblies

Yao Y.; Li J.-L.; Zhou Q.-Q.; Dong L.; Chen Y.-C.

首页> 外文期刊>Chemistry: A European journal >Enantioselective aza-Morita-Baylis-Hillman reaction with ketimines and acrolein catalyzed by organic assemblies

【24h】

Enantioselective aza-Morita-Baylis-Hillman reaction with ketimines and acrolein catalyzed by organic assemblies

机译：有机组装体催化酮亚胺和丙烯醛的对映选择性氮杂-Morita-Baylis-Hillman反应

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Some assembly required: The first enantioselective aza-Morita-Baylis- Hillman (MBH) reaction with imines of β,γ-unsaturated α-ketoesters and acrolein was developed. The transformation is catalyzed by a combined system of β-ICD and (R)-BINOL (1) or a bifunctional tertiary amine-thiourea 2. Experimental results and preliminary spectroscopy studies demonstrated that self-assembly between β-ICD and the additive may occur, which then promotes the asymmetric aza-MBH reaction through a synergistic activation mode.

机译：需要进行一些组装：开发了第一个对映选择性氮杂-Morita-Baylis-Hillman（MBH）与β，γ-不饱和α-酮酸酯和丙烯醛的亚胺反应。 β-ICD和（R）-BINOL（1）或双功能叔胺-硫脲2的组合系统可催化该转化。实验结果和初步光谱研究表明，β-ICD与添加剂之间可能发生自组装。，然后通过协同激活模式促进不对称aza-MBH反应。

著录项

来源
《Chemistry: A European journal》 |2013年第29期|共5页
作者
Yao Y.; Li J.-L.; Zhou Q.-Q.; Dong L.; Chen Y.-C.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
β-isocupreidine; acrolein; aza-Morita-Baylis-Hillman; ketimines; organocatalysis; synthetic methods;

机译：β-异cupreidine;丙烯醛;Aza-Morita-Baylis-Hillman;酮亚胺;有机催化;合成方法;

相似文献

外文文献
中文文献
专利

1. Enantioselective aza-Morita-Baylis-Hillman reaction with ketimines and acrolein catalyzed by organic assemblies [J] . Yao Y., Li J.-L., Zhou Q.-Q., Chemistry: A European journal . 2013,第29期

机译：有机组装体催化酮亚胺和丙烯醛的对映选择性氮杂-Morita-Baylis-Hillman反应
2. Enantioselective aza-Morita-Baylis-Hillman reaction between acrylates and N-Boc isatin ketimines: asymmetric construction of chiral 3-substituted-3-aminooxindoles [J] . Xuan Zhao, Tian-Ze Li, Jing-Ying Qian, Organic & biomolecular chemistry . 2014,第40期

机译：丙烯酸酯和N-Boc Isatin酮亚胺之间的对映选择性aza-Morita-Baylis-Hillman反应：手性3-取代-3-氨基恶吲哚的不对称结构
3. Enantioselective Aza-Morita-Baylis-Hillman Reactions of Acrylonitrile Catalyzed by Palladium(II) Pincer Complexes having C2-Symmetric Chiral Bis(imidazoline) Ligands [J] . Kengo Hyodo, Shuichi Nakamura, Norio Shibata Angewandte Chemie . 2012,第41期

机译：含C2-对称手性双（咪唑啉）配体的钯（II）钳配合物催化丙烯腈的对映选择性Aza-Morita-Baylis-Hillman反应
4. Enantioselective Mannich Reaction of Z-Ketimines Using a Secondary Amine Catalyst [C] . Chihiro Homma, Hiroki Maruyama, Taichi Kano 日本化学会春季年会講演予稿集 . 2018

机译：使用仲胺催化剂的Z-酮胺对Z-ketimines的对映选择性的曼尼希反应
5. Stereoselective reactions of esters/amides and their surrogates catalyzed by bifunctional organocatalysts and enantioselective separation of secondary alcohols by hydrogenbonded organic framework. [D] . Guang, Jie. 2014

机译：双功能有机催化剂催化的酯/酰胺及其替代物的立体选择反应，以及氢键键合的有机骨架对仲醇的对映选择性分离。
6. Bi(III)-Catalyzed Enantioselective Allylation Reactions of Ketimines [O] . Jie Wang, Qingxia Zhang, Biying Zhou, 2019

机译：Bi（III）催化的Ketimines对映选择性烯丙基化反应
7. Chiral Brønsted acid-catalyzed enantioselective Friedel–Crafts reaction of 2-methoxyfuran with aliphatic ketimines generated in situ [O] . Azusa Kondoh, Yusuke Ota, Takazumi Komuro, 2016

机译：手性Brønsted酸催化的映选择性Friedel-Crafter 2-甲氧基呋喃的反应与原位产生的脂族ketimines

Enantioselective aza-Morita-Baylis-Hillman reaction with ketimines and acrolein catalyzed by organic assemblies

摘要

著录项

相似文献

相关主题

期刊订阅