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首页> 外文期刊>Chemistry: A European journal >Pillararene-Based Assemblies: Design Principle, Preparation and Applications
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Pillararene-Based Assemblies: Design Principle, Preparation and Applications

机译：基于Pillararene的组件：设计原理，制备和应用

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摘要

In this review, we highlight recent advancements on pillararene-based assemblies. The driving forces for the formation of the pillararene-based assemblies are discussed first. The host–guest interactions are deemed as not only general strategy for constructing assemblies but also essential components for preventing the assemblies from the dissociation. Solvent effect is also important in the assembling process, since it could influence the host– guest interactions and provide solvophobic effect on pillararenes for the assembly. Then, several pillararenebased assembly architectures are introduced, including pillararene- based interlocked structures, such as (poly)pseudorotaxanes, (poly)rotaxanes, and daisy chains, classified by their topological structures and synthetic strategy. The morphologies of the supramolecular assemblies are divided into several types, for example, nanospheres, nanotubes and supramolecular polymers. Furthermore, the functions and potential applications are summarized accompanied with related assembly structures. The review not only provides fundamental findings, but also foresights future research directions in the research area of pillararene-based assemblies.
机译：在这篇综述中，我们重点介绍了基于柱芳烃的组装技术的最新进展。首先讨论了基于柱状芳烃基团形成的驱动力。主客互动不仅是构建程序集的一般策略，而且是防止程序集分离的重要组成部分。溶剂效应在组装过程中也很重要，因为它可能影响主体与客体的相互作用，并在组装的柱芳烃上提供疏溶剂效应。然后，介绍了几种基于柱状芳烃的组装体系结构，包括基于柱状芳烃的互锁结构，例如（聚）假轮烷，（聚）轮烷和菊花链，并按其拓扑结构和合成策略进行了分类。超分子组装体的形态分为几种类型，例如，纳米球，纳米管和超分子聚合物。此外，还总结了功能和潜在的应用以及相关的组装结构。这篇综述不仅提供了基本的发现，而且还展望了基于柱碳烯的组件研究领域的未来研究方向。

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