Switchable Stereocontrolled Divergent Synthesis Induced by azaMichael Addition of Deactivated Primary Amines under Acid Catalysis

Amara Z.; Drege E.; Troufflard C.; Retailleau P.; Huu-Dau M. -E. Tran; Joseph D.

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Switchable Stereocontrolled Divergent Synthesis Induced by azaMichael Addition of Deactivated Primary Amines under Acid Catalysis

机译：酸催化失活伯胺的azaMichael加成诱导的可切换立体控制发散性合成

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Switchable tandem intramolecular aza-Michael/ Michael and double aza-Michael reactions allow the oriented synthesis of highly functionalised cyclic skeletons. Conjugate addition of deactivated anilines triggers chemo-and stereodivergent ring-closure reaction pathways with a striking selectivity depending on reaction conditions.

机译：可切换的串联分子内氮杂-迈克尔/迈克尔和双氮杂-迈克尔反应允许定向合成高度官能化的环状骨架。结合添加失活的苯胺会根据反应条件以惊人的选择性触发化学和立体发散的闭环反应途径。

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《Chemistry: A European journal》 |2014年第48期|共9页
作者
Amara Z.; Drege E.; Troufflard C.; Retailleau P.; Huu-Dau M. -E. Tran; Joseph D.;
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正文语种 eng
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关键词
chemoselectivity; cyclization; diastereoselectivity; enones; Michael addition;

机译：化学选择性;环化;非对映选择性;烯类;迈克尔加成;

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1. Switchable Stereocontrolled Divergent Synthesis Induced by azaMichael Addition of Deactivated Primary Amines under Acid Catalysis [J] . Amara Z., Drege E., Troufflard C., Chemistry: A European journal . 2014,第48期

机译：酸催化失活伯胺的azaMichael加成诱导的可切换立体控制发散性合成
2. Highly Enantioselective Synthesis of gamma-Nitro Heteroaromatic Ketones in a Doubly Stereocontrolled Manner Catalyzed by Bifunctional Thiourea Catalysts Based on Dehydroabietic Amine: A Doubly Stereocontrolled Approach to Pyrrolidine Carboxylic Acids [J] . Jiang XX, Zhang YF, Chan ASC, Organic letters . 2009,第1期

机译：脱氢松香胺双功能硫脲催化剂在双立体控制方式下高对映体选择性合成γ-硝基杂芳族酮：双立体控制吡咯烷羧酸的方法
3. A new photoclick reaction strategy: photo-induced catalysis of the thiol-Michael addition via a caged primary amine [J] . Weixian Xi, Matthias Krieger, Christopher J. Kloxin, Chemical Communications . 2013,第40期

机译：一种新的光点击反应策略：通过笼蔽的伯胺光诱导的巯基-迈克尔加成催化
4. SYNTHESIS OF BIOREDUCIBLE AND ACID LABILE POLY(AMIDO AMINE)S VTA MICHAEL-ADDITION REACTIONS AND THEIR APPLICATION IN GENE DELIVERY [C] . Zhiqiang Yu, Junjie Yan, Yezi You Symposium on innovative polymers for controlled delivery: Abstract book. . 2010

机译：可生物合成和酸性的脂族聚（酰胺基胺）VTA迈克尔-加成反应及其在基因传递中的应用
5. Synthesis of primary amine- and glyco-based methacrylamide polymers via the reversible addition-fragmentation chain transfer process. [D] . Deng, Zhicheng. 2008

机译：通过可逆的加成-断裂链转移过程合成伯胺和基于糖的甲基丙烯酰胺聚合物。
6. Reagent-controlled enantioselectivity switch for the asymmetric fluorination of β-ketocarbonyls by chiral primary amine catalysis [O] . Yangen You, Long Zhang, Sanzhong Luo 2017

机译：试剂控制的对映选择性开关用于手性伯胺催化β-酮羰基的不对称氟化
7. Highly enantioselective synthesis of γ-nitro heteroaromatic ketones in a doubly stereocontrolled manner catalyzed by bifunctional thiourea catalysts based on dehydroabietic amine : a doubly stereocontrolled approach to pyrrolidine carboxylic acids [O] . Jiang XX, Zhang YF, Chan ASC, 2009

机译：基于脱氢松香胺的双官能硫脲催化剂以双立体控制方式高对映选择性合成γ-硝基杂芳族酮：吡咯烷羧酸的双立体控制方法

Switchable Stereocontrolled Divergent Synthesis Induced by azaMichael Addition of Deactivated Primary Amines under Acid Catalysis

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