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Bidirectional photomagnetic conversions in a spin-crossover complex with a diarylethene moiety

机译:具有二芳基乙烯部分的自旋交联络合物中的双向光电转换

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摘要

Magnetic switch: An iron(II) complex with a diarylethene moiety was synthesized and its magnetic properties were investigated. The complex exhibited four unique electronic states based on high- and low-spin iron(II), as well as open- and closed-forms of the diarylethene moiety (see scheme). The complex showed switchable spin states based on light-induced excited-spin-state trapping in the solid state, as well as through photocyclization reactions in butyronitrile.
机译:磁性开关:合成具有二芳基乙烯部分的铁(II)配合物,并研究其磁性。该复合物表现出基于高和低自旋铁(II)以及二芳基乙烯部分的开放形式和封闭形式的四个独特的电子态(请参见示意图)。该络合物显示出基于固态的光诱导的激发自旋态俘获以及通过丁腈中的光环化反应而可切换的自旋态。

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