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Oxidation of Benzyl Alcohol and Carbon Monoxide Using Gold Nanoparticles Supported on MnO_2 Nanowire Microspheres

机译:MnO_2纳米线微球上负载的金纳米粒子氧化苄醇和一氧化碳

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摘要

MnO_2 was synthesised as a catalyst support material using a hydrothermal method. This involved reacting MnSO_4?H_2O and (NH_4)_2S_2O_8 at 120 ℃ for a range of crystallisation times, which affords control over the morphology and phase composition of the MnO_2 formed. Gold was deposited on these supports using sol-immobilisation, impregnation and deposition precipitation methods, and the resultant materials were used for the oxidation of benzyl alcohol and carbon monoxide. The effect of the support morphology on the dispersion of the gold nanoparticles and the consequent effect on the catalytic performance is described and discussed.
机译:使用水热法合成了MnO_2作为催化剂载体材料。这涉及到MnSO_4?H_2O和(NH_4)_2S_2O_8在120℃下反应一定的结晶时间,从而可以控制所形成的MnO_2的形态和相组成。使用溶胶固定化,浸渍和沉积沉淀法将金沉积在这些载体上,并将所得材料用于苯甲醇和一氧化碳的氧化。描述和讨论了载体形态对金纳米颗粒分散的影响以及对催化性能的影响。

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