Rational Design of a Face-Centred Square-Cuboid Coordination Cage

Muxin Han; Reent Michel; Guido H. Clever

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Rational Design of a Face-Centred Square-Cuboid Coordination Cage

机译：以面为中心的方形立方体协调笼的合理设计

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The simple synthetic conversion of a 90°-angled bis-pyridyl ligand into a tripodal tris-pyridyl ligand leads to the formal transformation of a cubic (a=b=c) into a square-cuboid (a=b≠ c) coordination cage. Mathematical considerations associated with the ligand design, together with X-ray structure results, NMR spectroscopic and mass spectrometric characterization and molecular modeling of both coordination cages are presented and discussed.

机译：90°角双吡啶基配体的简单合成转化为三脚架三吡啶基配体导致立方（a = b = c）正式转变为方立方（a = b≠c）配位笼。提出并讨论了与配体设计有关的数学考虑，以及X射线结构结果，NMR光谱和质谱表征以及两个配位笼的分子模型。

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《Chemistry: A European journal》 |2014年第34期|共5页
作者
Muxin Han; Reent Michel; Guido H. Clever;
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正文语种 eng
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cage compounds; coordination chemistry; palladium; self-assembly; supramolecular chemistry;

机译：笼状化合物;配位化学;钯;自组装;超分子化学;

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1. Rational Design of a Face-Centred Square-Cuboid Coordination Cage [J] . Muxin Han, Reent Michel, Guido H. Clever Chemistry: A European journal . 2014,第34期

机译：以面为中心的方形立方体协调笼的合理设计
2. Imposing control on self-assembly: rational design and synthesis of a mixed-metal, mixed-ligand coordination cage containing four types of component [J] . Metherell Alexander J., Ward Michael D. Chemical science . 2016,第2期

机译：对自组装施加控制：包含四种类型成分的混合金属混合配体协调笼的合理设计和合成
3. Imposing control on self-assembly: rational design and synthesis of a mixed-metal, mixed-ligand coordination cage containing four types of component [J] . Alexander J. Metherell, Michael D. Ward Chemical science . 2016,第2期

机译：对自组装施加控制：包含四种类型成分的混合金属混合配体协调笼的合理设计和合成
4. Effective Coordination Based Descriptors for Rational Design of Metal Nanocatalysts [C] . Xianfeng Ma, Siwen Wang, Hongliang Xin AIChE Annual Meeting . 2016

机译：金属纳米催化剂合理设计的基于有效的基于协调的描述符
5. Rational derational design of closed shell, dicyanoaurate-containing coordination polymers for materials applications [D] . Katz, Michael J. 2009

机译：闭壳含二氰基金酸酯的配位聚合物的合理减量设计
6. Imposing control on self-assembly: rational design and synthesis of a mixed-metal mixed-ligand coordination cage containing four types of component [O] . Alexander J. Metherell, Michael D. Ward 2016

机译：对自组装施加控制：包含四种类型成分的混合金属混合配体协调笼的合理设计和合成
7. Rational Design of an Amphiphilic Coordination Cage-Based Emulsifier [O] . Subhadeep Saha, Björn Holzapfel, Yen-Ting Chen, 2018

机译：两亲协调笼系乳化剂的理性设计

Rational Design of a Face-Centred Square-Cuboid Coordination Cage

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