A Stable Microporous Mixed-Metal Metal–Organic Framework with Highly Active Cu~(2+) Sites for Efficient Cross-Dehydrogenative Coupling Reactions

Xiu-Li Yang; Chao Zou; Yabing He; Min Zhao; Banglin Chen; Shengchang Xiang; Michael OKeeffe; Chuan-De Wu

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A Stable Microporous Mixed-Metal Metal–Organic Framework with Highly Active Cu~(2+) Sites for Efficient Cross-Dehydrogenative Coupling Reactions

机译：具有高活性Cu〜（2+）位的稳定的微孔混合金属金属有机骨架，可进行高效的脱氢偶联反应

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Two metalloporphyrin octacarboxylates were used to link copper(II) nodes for the formation of two novel porous mixed-metal metal–organic frameworks (M'MOFs) containing nanopore cages (2.1 nm in diameter) or nanotubular channels (1.5 nm in diameter). The highly active Cu~(2+) sites on the nanotubular surfaces of the stable porous M'MOF ZJU-22, stabilized by three-connected nets, lead to the superior catalytic activity for the cross-dehydrogenative coupling (CDC) reaction

机译：两种金属卟啉八羧酸盐用于连接铜（II）节点，以形成两种新型的多孔混合金属金属-有机骨架（M'MOF），这些骨架包含纳米孔笼（直径2.1 nm）或纳米管通道（直径1.5 nm）。稳定的多孔M'MOF ZJU-22纳米管表面上的高活性Cu〜（2+）位点通过三连接网稳定化，从而为交叉脱氢偶联（CDC）反应带来了卓越的催化活性

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来源
《Chemistry: A European journal》 |2014年第5期|共6页
作者
Xiu-Li Yang; Chao Zou; Yabing He; Min Zhao; Banglin Chen; Shengchang Xiang; Michael OKeeffe; Chuan-De Wu;
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正文语种 eng
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cross-coupling; heterogeneous catalysis; metal– organic frameworks; microporous materials; porphyrinoids;

机译：交叉耦合;非均相催化;金属有机骨架;微孔材料;卟啉;

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1. A Stable Microporous Mixed-Metal Metal–Organic Framework with Highly Active Cu~(2+) Sites for Efficient Cross-Dehydrogenative Coupling Reactions [J] . Xiu-Li Yang, Chao Zou, Yabing He, Chemistry: A European journal . 2014,第5期

机译：具有高活性Cu〜（2+）位的稳定的微孔混合金属金属有机骨架，可进行高效的脱氢偶联反应
2. A microporous luminescent metal-organic framework for highly selective and sensitive sensing of Cu~(2+) in aqueous solutionf [J] . Yunqing Xiao, Yuanjing Cui, Qian Zheng, Chemical Communications . 2010,第30期

机译：用于水溶液中Cu〜（2+）的高选择性和灵敏感测的微孔发光金属有机框架f
3. Highly active palladium nanoparticles immobilized on knitting microporous organic polymers as efficient catalysts for Suzuki-Miyaura cross-coupling reaction [J] . Song Kunpeng, Liu Peng, Wang Jingyu, Journal of porous materials . 2016,第3期

机译：固定在编织微孔有机聚合物上的高活性钯纳米粒子，作为铃木-宫浦交叉偶联反应的有效催化剂
4. Attempts of Removal of Heavy Metal Cations (Cu~2+, Zn~2+, Ni~2+) From Industrial Wastewaters by Coupling Filtration and Solvent Extraction Processes [C] . Michel Persin, Jean Sarrazin, Andre Larbot, Preprints of International Conference on Membrane Science and Technology (ICMST'98) June 9-13, 1998 Beijing, China . 1998

机译：耦合过滤与溶剂萃取法去除工业废水中重金属阳离子（Cu〜2 +，Zn〜2 +，Ni〜2 +）的尝试
5. Design and synthesis of ferrocenylmethylphosphines for transition metal catalysis: From highly active cross -coupling catalysts to highly efficient addition reaction catalysts [D] . Lu, Yong 2007

机译：用于过渡金属催化的二茂铁基甲基膦的设计与合成：从高活性的交叉偶联催化剂到高效的加成反应催化剂
6. Microporous metal–organic framework with dual functionalities for highly efficient removal of acetylene from ethylene/acetylene mixtures [O] . Tong-Liang Hu, Hailong Wang, Bin Li, -1

机译：具有双重功能的微孔金属-有机骨架可从乙烯/乙炔混合物中高效去除乙炔
7. Highly Active and Stable Single-Atom Cu Catalysts Supported by a Metal–Organic Framework [O] . Ali M. Abdel-Mageed, Bunyarat Rungtaweevoranit, Magdalena Parlinska-Wojtan, 2019

机译：高活性和稳定的单原子Cu催化剂由金属有机框架支撑

A Stable Microporous Mixed-Metal Metal–Organic Framework with Highly Active Cu~(2+) Sites for Efficient Cross-Dehydrogenative Coupling Reactions

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