Cooperative Effect of Two Metals: CoPd(OAc)_4-Catalyzed C-H Amination and Aziridination

Guan-Hao Huang; Jian-Min Li; Jing-Jyun Huang; Jyun-Dai Lin; Gary Jing Chuang

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Cooperative Effect of Two Metals: CoPd(OAc)_4-Catalyzed C-H Amination and Aziridination

机译：两种金属的协同作用：CoPd（OAc）_4-催化的C-H胺化和叠氮化

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The first Co/Pd-cocatalyzed intramolecular C-H amination and aziridination reactions were developed. Sulfa mate esters were converted to oxathiazinanes by using CoPd(OAc)_4 as catalyst and Phl(OAc)_2 as oxidant. The mutual presence of both Co and Pd is crucial for the catalytic activity. This combination of two metals with simple acetate ligands provides an economical alternative to the Rh-catalyzed insertion of nitrenoids into C-H bonds.

机译：研发了第一批Co / Pd共催化的分子内C-H氨基化和叠氮化反应。通过使用CoPd（OAc）_4作为催化剂和Phl（OAc）_2作为氧化剂，将亚磺酸酯酯转化为恶噻嗪酮。 Co和Pd的共同存在对于催化活性至关重要。两种金属与简单的乙酸盐配体的这种结合为Rh催化的类胡萝卜素插入C-H键提供了一种经济的选择。

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《Chemistry: A European journal》 |2014年第18aep期|共4页
作者
Guan-Hao Huang; Jian-Min Li; Jing-Jyun Huang; Jyun-Dai Lin; Gary Jing Chuang;
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正文语种 eng
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amination; cobalt; heterometallic complexes; palladium; synthetic methods;

机译：胺化;钴;异金属配合物;钯;合成方法;

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1. Cooperative Effect of Two Metals: CoPd(OAc)_4-Catalyzed C-H Amination and Aziridination [J] . Guan-Hao Huang, Jian-Min Li, Jing-Jyun Huang, Chemistry: A European journal . 2014,第18aEP期

机译：两种金属的协同作用：CoPd（OAc）_4-催化的C-H胺化和叠氮化
2. Key mechanistic insights into the intramolecular C-H bond amination and double bond aziridination in sulfamate esters catalyzed by dirhodium tetracarboxylate complexes [J] . Varela-Alvarez Adrian, Haines Brandon E., Musaev Djamaladdin G. Journal of Organometallic Chemistry . 2018,第期

机译：狄甲酸酯复合物催化氨基酯酯中的分子内C-H键胺化和双键氮化的关键机械洞察
3. A Versatile Tripodal Cu(Ⅰ) Reagent for C-N Bond Construction via Nitrene-Transfer Chemistry: Catalytic Perspectives and Mechanistic Insights on C-H Aminations/Amidinations and Olefin Aziridinations [J] . Vivek Bagchi, Patrina Paraskevopoulou, Purak Das, Journal of the American Chemical Society . 2014,第32期

机译：用于通过丁二烯转移化学构建C-N键的多功能三脚架Cu（Ⅰ）试剂：C-H氨基化/酰胺化和烯烃叠氮化的催化观点和机理研究
4. Capturing All the Major Fleeting Intermediates of a Catalytic Cycle Using Desorption Electrospray Ionization: C-H Amination [C] . Richard H. Perry, Thomas J. Cahill III, Jennifer L. Roizen, American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2012

机译：使用解吸电喷雾电离捕获催化循环的所有主要短暂中间体：C-H胺化
5. Application of Nitrene Transfer Reactions for Streamlining Amine Synthesis Part One: Development of C–H Amination via Metal-Catalyzed Nitrene Transfer Part Two: Stereocontrolled 4pi-Electrocyclization via Eneallene Aziridination [D] . Corbin, Joshua Robert. 2020

机译：硝酸硝基转移反应在精简胺合成中的应用部分：通过金属催化的硝酸丁烯转移第2部分进行C-H胺化：通过Eneallensαziridination立体控制4PI电循环
6. Arene C-H Amination at Nickel in Terphenyl Diphosphine Complexes with Labile Metal-Arene Interactions [O] . Dr. David E. Herbert, Nadia C. Lara, Prof. Theodor Agapie -1

机译：具有不稳定金属-芳烃相互作用的三联苯二膦配合物中镍的芳烃C-H胺化
7. Aziridination and amidation reaction mediated by polymer-supported metalloporphyrins with PhI(OAc)2 and TsNH2 [O] . Zhi-Wang Zhou, Yuan-Cong Zhao, Yang Yue, 2005

机译：聚合物负载的金属卟啉与phI（Oac）2和TsNH2介导的氮化物和酰胺化反应
8. Halomethyl-Metal Compounds. LVII. The Insertion of Phenyl (Bromodichloromethyl)Mercury-Derived Dichlorocarbene into C-H Bonds. Further Studies of the Beta-Metal Activated C-H Insertion Reaction. [R] . Seyferth, D., Cheng, Y. M., Traficante, D. D. 1972

机译：卤甲基金属化合物。 LVII。将苯基（溴二氯甲基）汞衍生的二氯卡宾插入C-H键中。 β-金属活化C-H插入反应的进一步研究。

Cooperative Effect of Two Metals: CoPd(OAc)_4-Catalyzed C-H Amination and Aziridination

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