Synthesis of Periphery-Decorated and Core-Initiated Borane Polyanionic Macromolecules

Teixidor Francesc; Pepiol Ariadna; Vinas Clara

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Synthesis of Periphery-Decorated and Core-Initiated Borane Polyanionic Macromolecules

机译：外围装饰和核引发的硼烷聚阴离子大分子的合成

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A new class of globular polybranched macromolecules that contain multiple anionic metallacarborane clusters at the o-carborane periphery is reported. The water soluble high boron rich containing molecules could be of interest for boron neutron capture therapy (BNCT) as well as for drug delivery. The reinforced electrostatic noncovalent interactions between anionic polyethylene glycol cobaltabisdicarbollide (PEG-COSAN) branches and the ammonium cation have been shown using ESI-MS.

机译：据报道，一类新型的球状多支化大分子在邻-碳硼烷外围含有多个阴离子金属碳硼烷簇。水溶性高含硼量高的分子可能对硼中子俘获疗法（BNCT）以及药物递送很感兴趣。阴离子聚乙二醇钴双二糖脂（PEG-COSAN）支链和铵阳离子之间的增强静电非共价相互作用已通过ESI-MS显示。

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《Chemistry: A European journal》 |2015年第30期|共4页
作者
Teixidor Francesc; Pepiol Ariadna; Vinas Clara;
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正文语种 eng
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关键词
carborane; cobaltabisdicarbollide; macromolecules; polyanions; polybranched;

机译：碳硼烷;钴双二糖;大分子;聚阴离子;聚支;

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1. Synthesis of Periphery-Decorated and Core-Initiated Borane Polyanionic Macromolecules [J] . Teixidor Francesc, Pepiol Ariadna, Vinas Clara Chemistry: A European journal . 2015,第30期

机译：外围装饰和核引发的硼烷聚阴离子大分子的合成
2. Telechelic Helical Poly(quinoxaline-2,3-diyl)s Containing a Structurally Defined, Circularly Polarized Luminescent Terquinoxaline Core: Synthesis by Core-Initiated Bidirectional Living Polymerization [J] . Kuriyama Shogo, Nagata Yuuya, Suginome Michinori ACS Macro Letters . 2019,第4期

机译：TeleCelic螺旋聚（喹喔啉-2,3-亚基）S含有结构定义的圆偏振发光Terquinoxaline核心：通过核心引发的双向生物聚合合成
3. New strategy to the synthesis of (N -> B) phenyl[N-alkyliminodiacetate-O,O ',N]boranes: The crystal structure of (N -> B) phenyl[N-benzyliminodiacetate-O,O ',N]borane, (N -> B)phenyl[N-(4-methyl)benzyliminodiacetate-O,O ',N]borane and (N -> B) phenyl[N-phenacyliminodiacetate-O,O ',N]borane [J] . Percino TM, Ancona RMF, Martinez ML Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2009,第13期

机译：合成（N-> B）苯基[N-烷基亚氨基二乙酸酯-O，O'，N]硼烷的新策略：（N-> B）苯基[N->苄基亚氨基二乙酸酯-O，O'，N]的晶体结构硼烷，（N-> B）苯基[N-（4-甲基）苄基亚氨基二乙酸酯-O，O'，N]硼烷和（N-> B）苯基[N-苯乙酰亚胺二乙酸酯-O，O'，N]硼烷
4. Ca_(0.5)Mg_(0.5)Co_2O_4 Nanosheets Comprised of Nanoparticles, Synthesis, Characterization and their Catalytic Activity in the Hydrolysis of Ammonia Borane for Hydrogen Production [C] . Liling LI, Xiuxia FENG, Jinyun LIAO, International Conference on Material Engineering and Application . 2018

机译：CA_（0.5）Mg_（0.5）CO_2O_4纳米蛋白酶组成，其组成纳米颗粒，合成，表征及其催化活性，用于氢生产的氨硼烷的水解中
5. Synthesis and ligand substitution in polyhedral borane anions and transition metal complexes of heteroatom borane cages. [D] . Jasper, Stephen Alan, Jr. 1995

机译：多面体硼烷阴离子和杂原子硼烷笼的过渡金属络合物中的合成和配体取代。
6. m-Carborane as a Novel Core for Periphery-Decorated Macromolecules [O] . Ines Bennour, Francesc Teixidor, Zsolt Kelemen, 2020

机译：M-Carborane作为外围装饰大分子的新型核心
7. Periphery Decorated and Core Initiated Neutral and Polyanionic Borane Large Molecules: Forthcoming and Promising Properties for Medicinal Applications [O] . Clara Viñas, Rosario Núñez, Ines Bennour, 2019

机译：周边装饰和核心发起中性和多阴离子硼烷大分子：即将到来和有希望的药用应用性能
8. Mechanisms and Processes for Conversion of Smaller Boranes to Larger Boranes or Borane Fragments [R] . Parry, R. W., Kodama, G. 1980

机译：将较小的硼烷转化为较大的硼烷或硼烷碎片的机制和过程

Synthesis of Periphery-Decorated and Core-Initiated Borane Polyanionic Macromolecules

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