Metal-Organic Frameworks (MOFs) as Multivalent Materials: Size Control and Surface Functionalization by Monovalent Capping Ligands

Rijnaarts Timon; Mejia-Ariza Raquel; Egberink Richard J. M.; van Roosmalen Wies; Huskens Jurriaan

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Metal-Organic Frameworks (MOFs) as Multivalent Materials: Size Control and Surface Functionalization by Monovalent Capping Ligands

机译：金属有机框架（MOF）作为多价材料：通过单价封端配体进行尺寸控制和表面功能化

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Control over particle size and composition are pivotal to tune the properties of metal organic frameworks (MOFs), for example, for biomedical applications. Particle-size control and functionalization of MIL-88A were achieved by using stoichiometric replacement of a small fraction of the divalent fumarate by monovalent capping ligands. A fluorine-capping ligand was used to quantify the surface coverage of capping ligand at the surface of MIL-88A. Size control at the nanoscale was achieved by using a monovalent carboxylic acid-functionalized poly(ethylene glycol) (PEG-COOH) ligand at different concentrations. Finally, a biotin-carboxylic acid capping ligand was used to functionalize MIL-88A to bind fluorescently labeled streptavidin as an example towards bioapplications.

机译：控制粒径和组成对于调节金属有机骨架（MOF）的性能至关重要，例如用于生物医学应用。 MIL-88A的粒度控制和功能化是通过用一价封端配体化学计量替代一小部分二价富马酸酯来实现的。封氟配体用于定量MIL-88A表面封盖配体的表面覆盖率。通过使用不同浓度的一价羧酸官能化的聚乙二醇（PEG-COOH）配体，可以实现纳米级的尺寸控制。最后，生物素-羧酸封端配体被用于功能化MIL-88A以结合荧光标记的链霉亲和素，作为生物应用的一个例子。

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《Chemistry: A European journal》 |2015年第29期|共6页
作者
Rijnaarts Timon; Mejia-Ariza Raquel; Egberink Richard J. M.; van Roosmalen Wies; Huskens Jurriaan;
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正文语种 eng
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capping ligands; metal-organic frameworks; multivalent materials; nanoparticles; supramolecular chemistry;

机译：封端配体;金属有机骨架;多价材料;纳米粒子;超分子化学;

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1. Metal-Organic Frameworks (MOFs) as Multivalent Materials: Size Control and Surface Functionalization by Monovalent Capping Ligands [J] . Rijnaarts Timon, Mejia-Ariza Raquel, Egberink Richard J. M., Chemistry: A European journal . 2015,第29期

机译：金属有机框架（MOF）作为多价材料：通过单价封端配体进行尺寸控制和表面功能化
2. PolyMOF Nanoparticles: Dual Roles of a Multivalent polyMOF Ligand in Size Control and Surface Functionalization [J] . Angewandte Chemie . 2019,第46期

机译：纳米颗粒的Polymof纳米颗粒：大小控制和表面官能化的多价聚合物配体的双重作用
3. Ligand-Functionalization-Controlled Activity of Metal-Organic Framework-Encapsulated Pt Nanocatalyst toward Activation of Water [J] . Ogiwara Naoki, Kobayashi Hirokazu, Inuka Munehiro, Nano letters . 2020,第1期

机译：金属 - 有机骨架 - 包封PT纳米催化剂朝向激活水的配体 - 官能化控制活性
4. Precisely Size-controlled Metal Nanopartlcles (Au, Pd andPt) Inserted into Metal-Organic Frameworks (MOFs):Synthesis and Catalytic Properties [C] . Sudoral Yadnum, Pipat Khongpracha, Chompunuch Warakulwit American Chemical Society National Meeting . 2011

机译：插入金属 - 有机框架（MOFS）中的精确尺寸控制的金属纳米粉末（AU，PD ANDPT）：合成和催化性能
5. Synthesis, characterization, and catalytic performance of metal-organic frameworks (MOFs) and MOF-templated materials [D] . McNamara, Nicholas Dennis 2015

机译：金属有机骨架（MOF）和MOF模板材料的合成，表征和催化性能
6. Multifunctional Supramolecular Hybrid Materials Constructed from Hierarchical Self-Ordering of In Situ Generated Metal-Organic Framework (MOF) Nanoparticles [O] . Abhijeet K Chaudhari, Intaek Han, Jin-Chong Tan -1

机译：从原位生成的金属有机骨架（MOF）纳米粒子的分层自排序构造的多功能超分子杂化材料。
7. Cover Feature: Solvent-Induced Cadmium(II) Metal-Organic Frameworks with Adjustable Guest-Evacuated Porosity: Application in the Controllable Assembly of MOF-Derived Porous Carbon Materials for Supercapacitors (Chem. Eur. J. 62/2017) [O] . Man-Li Yue, Yi-Fan Jiang, Lin Zhang, 2017

机译：封面特征：溶剂诱导的镉（II）金属有机框架，具有可调节的客人疏散孔隙度：在SuperCapacitors（Chem.EUR.J.62 / 2017）的Mof衍生多孔碳材料的可控组装中的应用

Metal-Organic Frameworks (MOFs) as Multivalent Materials: Size Control and Surface Functionalization by Monovalent Capping Ligands

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