首页> 外文期刊>Chemistry: A European journal >An Independent 1D Single-Walled Metal-Organic Nanotube Transformed from a 2D Layer Exhibits Highly Selective and Reversible Sensing of Nitroaromatic Compounds
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An Independent 1D Single-Walled Metal-Organic Nanotube Transformed from a 2D Layer Exhibits Highly Selective and Reversible Sensing of Nitroaromatic Compounds

机译:从2D层转换而来的独立一维单壁金属有机纳米管展现出硝基芳香族化合物的高度选择性和可逆性。

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摘要

The syntheses and structures of two new ZnII complexes, a 2D graphite-like layer {[Zn(PIA)H_2O]·H_2O}_n (1) and an independent 1D single-walled metal-organic nanotube (SWMONT) {[Zn_2(PIA)_2(bpy)_2]·2.5H_2O·DMA}_n (2), have been reported based on a "Y"-shaped 5-(pyridine-4-%%%yl)isophthalic acid ligand (H_2PIA). Interestingly, the 2D graphite-like layer in 1 can transform into the independent 1D SWMONT in 2 with addition of 2,2'-bipyridine (bpy), which represents the first successfully experimental example of an independent 1D metal-organic nanotube generated from a 2D layer by a "rolling-up" mechanism.
机译:两种新型ZnII配合物的合成和结构,即二维石墨状层{[Zn(PIA)H_2O]·H_2O} _n(1)和独立的一维单壁金属有机纳米管(SWMONT){[Zn_2(PIA )_2(bpy)_2]·2.5H_2O·DMA} _n(2)据报道是基于“ Y”形的5-(吡啶-4-%%基)间苯二甲酸配体(H_2PIA)。有趣的是,添加了2,2'-联吡啶(bpy)的1D中的2D石墨状层可以转变为2中的独立1D SWMONT,这是第一个成功的实验实例,是由a 2D层采用“汇总”机制。

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