Efficient Domino Hydroformylation/Benzoin Condensation: Highly Selective Synthesis of alpha-Hydroxy Ketones

Dong Kaiwu; Sang Rui; Soule Jean-Francois; Bruneau Christian; Franke Robert; Jackstell Ralf; Beller Matthias

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Efficient Domino Hydroformylation/Benzoin Condensation: Highly Selective Synthesis of alpha-Hydroxy Ketones

机译：高效的多米诺加氢甲酰化/苄星缩合反应：α-羟基酮的高度选择性合成

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An improved domino hydroformylation/benzoin condensation to give alpha-hydroxy ketones has been developed. Easily available olefins are smoothly converted into the corresponding alpha-hydroxy ketones in high yields with excellent regioselectivities. Key to success is the use of a specific catalytic system consisting of a rhodium/phosphine complex and the CO2 adduct of an N-heterocyclic carbene.

机译：已经开发了改进的多米诺加氢甲酰化/安息香缩合以产生α-羟基酮。容易获得的烯烃可以以高收率平稳地转化为相应的α-羟基酮，并且具有出色的区域选择性。成功的关键是使用由铑/膦配合物和N-杂环卡宾的CO2加合物组成的特定催化体系。

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《Chemistry: A European journal》 |2015年第50期|共5页
作者
Dong Kaiwu; Sang Rui; Soule Jean-Francois; Bruneau Christian; Franke Robert; Jackstell Ralf; Beller Matthias;
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正文语种 eng
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关键词
benzoin condensation; catalysis; domino reactions; hydroformylation; olefins;

机译：安息香缩合;催化;多米诺反应;加氢甲酰化;烯烃;

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1. Efficient Domino Hydroformylation/Benzoin Condensation: Highly Selective Synthesis of alpha-Hydroxy Ketones [J] . Dong Kaiwu, Sang Rui, Soule Jean-Francois, Chemistry: A European journal . 2015,第50期

机译：高效的多米诺加氢甲酰化/苄星缩合反应：α-羟基酮的高度选择性合成
2. Domino-Hydroformylation/Aldol Condensation Catalysis: Highly Selective Synthesis of α,β-Unsaturated Aldehydes from Olefins [J] . Xianjie Fang, Ralf Jackstell, Robert Franke, Chemistry: A European journal . 2014,第41期

机译：多米诺加氢甲酰化/羟醛缩合催化：从烯烃中高选择性合成α，β-不饱和醛
3. Highly Efficient and Selective Synthesis of (E)-α,β-Unsaturated Ketones by Crossed Condensation of Ketones and Aldehydes Catalyzed by an Air-Stable Cationic Organobismuth Perfluorooctanesulfonate [J] . Renhua Qiu, Yimiao Qiu, Shuangfeng Yin Advanced synthesis & catalysis . 2010,第1期

机译：空气稳定的阳离子有机铋全氟辛烷磺酸催化的酮和醛的交叉缩合高效高效地选择性合成（E）-α，β-不饱和酮
4. Highly Efficient Synthesis of Silicon-containing (R)-ketone-cyanohydrin Catalyzed by (R)-hydroxynitrilase Lyase from Prunus Domestic [C] . Senlin Liu International Conference on Chemical Engineering and Advanced Materials . 2011

机译：高效合成含硅（R） - 酮 - 氰基醇催化（R） - 羟基硝基酶裂解酶，来自普鲁乌斯国内
5. Studies in polyketide synthesis: Development of a highly selective reduction of beta-alkoxy ketones, completion of the total synthesis of RK-397, and progress towards the total synthesis of arenolide. [D] . Cullen, Aaron J. 2006

机译：聚酮化合物合成的研究：开发高选择性还原β-烷氧基酮，完成RK-397的总合成，并朝着合成芳烃的方向发展。
6. Synthesis of (-)-Indolizidine 167B based on domino hydroformylation/cyclization reactions [O] . Giuditta Guazzelli, Raffaello Lazzaroni, Roberta Settambolo 2008

机译：基于多米诺加氢甲酰化/环化反应的（-）-吲哚并啶167B的合成
7. B2O3/Al2O3 as a new, highly efficient and reusable heterogeneous catalyst for the selective synthesis of β-enamino ketones and esters under solvent-free conditions [O] . Jiu-Xi Chen, Chang-Fu Zhang, Wen-Xia Gao, 2010

机译：B2O3 / Al 2O3作为一种新的高效可重复使用的非均相催化剂，用于在无溶剂条件下选择性合成β-烯氨基酮和酯

Efficient Domino Hydroformylation/Benzoin Condensation: Highly Selective Synthesis of alpha-Hydroxy Ketones

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