BN Heterosuperbenzenes: Synthesis and Properties

Wang Xiao-Ye; Wang Jie-Yu; Pei Jian

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BN Heterosuperbenzenes: Synthesis and Properties

机译：BN杂超苯：合成与性能

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Replacement of CC unit with its isoelectronic BN unit in aromatics provides a new class of molecules with appealing properties, which have attracted great attention recently. In this Concept, we focus on BN-substituted polycyclic aromatics with fused structures, and review their synthesis, photophysical, and redox properties, as well as their applications in organic electronics. We also present challenging synthetic targets, large BN- substituted polycyclic aromatics, such as regioregular BN heterosuperbenzenes, which can be viewed as BN-doped nanographenes. Finally, we propose an atomically precise bottom-up synthesis of structurally well-defined BN-doped graphenes.

机译：用芳香族化合物中的等电子BN单元代替CC单元可提供一类具有诱人特性的新型分子，近来引起了极大的关注。在本概念中，我们重点研究具有稠合结构的BN取代的多环芳烃，并综述其合成，光物理和氧化还原特性，以及它们在有机电子学中的应用。我们还提出了具有挑战性的合成目标，大型BN取代的多环芳族化合物，例如区域规则的BN杂超苯，可以被视为BN掺杂的纳米石墨烯。最后，我们提出了结构精确定义的BN掺杂石墨烯的原子精确自下而上的合成方法。

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《Chemistry: A European journal》 |2015年第9期|共12页
作者
Wang Xiao-Ye; Wang Jie-Yu; Pei Jian;
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正文语种 eng
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azaborine; boron; graphene; nitrogen; organic electronics; polycyclic aromatics;

机译：氮杂硼烷;硼;石墨烯;氮;有机电子学;多环芳烃;

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专利

1. A Straightforward Strategy toward Large BN-Embedded π-Systems: Synthesis, Structure, and Optoelectronic Properties of Extended BN Heterosuperbenzenes [J] . Xiao-Ye Wang, Fang-Dong Zhuang, Rui-Bo Wang, Journal of the American Chemical Society . 2014,第10期

机译：大型BN嵌入π系统的直接策略：扩展的BN杂超苯的合成，结构和光电性质
2. Synthesis and Properties of Bismuth Sodium Titanate (BNT) - Part II: Dielectric Properties of Sintered BNT and La-doped BNT [J] . P. Pookmanee, S. Phanichphant, U. Straube, Ceramic Forum International . 2003,第11期

机译：钛酸铋钠（BNT）的合成和性能-第二部分：烧结BNT和La掺杂BNT的介电性能
3. Synthesis, properties and crystal structures of alpha-Ca-3(BN2)(2) and Ca9+x(BN2,CBN)(6) - two compounds with BN2;(3-) and CBN4- anions [J] . Worle M., Nesper R., Altenschildesche HMZ. Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 1998,第1a2期

机译：α-Ca-3（BN2）（2）和Ca9 + x（BN2，CBN）（6）-具有BN2;（3-）和CBN4-阴离子的两种化合物的合成，性质和晶体结构
4. Synthesis and properties of BN, BCN and B/BN thin films deposited by ion beam sputtering method [C] . S. Kurooka, T. Ikeda, N. Iwamoto Minerals, Metals and Materials Society . 2000

机译：离子束溅射法沉积BN，BCN和B / BN薄膜的合成与性能
5. Synthesis and Characterization of BN-Tryptophan and Its Incorporation into Proteins & the Cation-π Binding Ability of BN-Indole [D] . Boknevitz, Katherine Lynn Michelle. 2020

机译：BN-色氨酸的合成与表征及其掺入BN-Indole的蛋白质和阳离子 - π结合能力
6. BN Embedded Polycyclic π-Conjugated Systems: Synthesis Optoelectronic Properties and Photovoltaic Applications [O] . Jianhua Huang, Yuqing Li 2018

机译：BN嵌入式多环π共轭系统：合成光电性质和光伏应用
7. Synthesis and properties of oligonucleotides containing novel 2',4'-BNA analogues (2',4'-BNACOC) [O] . Y. Hari, T. Osaki, K. Eguchi, 2002

机译：含有新型2'，4'-BNA类似物（2'，4'-Bnacoc）的寡核苷酸的合成与性质
8. Synthesis, Structure and Properties of BN Nanotubes, BN/SiC and CBN/SiC Micro/Nano-Whiskers [R] . Pokropyvnyy, V. 2003

机译：BN纳米管，BN / siC和CBN / siC微/纳米晶须的合成，结构与性能

BN Heterosuperbenzenes: Synthesis and Properties

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