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Molecular Chalcoxides (ChalcoPolyoxometalates): A Family of Functional Materials with Emergent Properties

机译:分子氧化硫(ChalcoPolyoxometalates):具有新兴特性的功能材料系列

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摘要

Molecular chalcoxides (chalcoPOMs; POMs = polyoxometalates), a recently discovered new family of compounds with well-defined building block attributes, are discussed in terms of developing new functional materials. This is because the combination of sulfur-containing metallo-dimers with highly condensed metallo-oxo units allows the assembly of new clusters with hybrid properties intermediate between those of polyoxometalates and chalcogenides. Moreover, the prospect that the molecular chalcoxides could be, excellent new models for a better understanding of chalcogenide's functionality, as well as promisjng candidates for the, development of new functional molecule-based or composite nanomaterials, is proposed. The concepts that support my aim for further development of the new family of molecular chalcoxides as functional materials and my vision for their potential implications in the materials chemistry are discussed.
机译:分子硫氧化物(chalcoPOMs; POMs =多金属氧酸盐)是一种新发现的具有明确结构单元属性的新化合物家族,目前正在开发新的功能材料。这是因为含硫的金属二聚体与高度缩合的金属-氧代单元的组合允许组装具有介于多金属氧酸酯和硫属元素化物之间的杂化性质的新簇。此外,提出了分子硫族化合物可能的前景,即用于更好地理解硫族化物功能的优良新模型,以及开发基于功能分子的新型或复合纳米材料的可能候选物。讨论了支持我进一步开发分子硫族氧化物作为功能材料的新目标的概念以及我对它们在材料化学中的潜在影响的愿景。

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