Synthesis of One-Dimensional Schiff Base Polymers that Contain an Oligothiophene Building Block on the Graphite Surface

Sun Xiu-Ling; Fan Li-Xia; Yang Yong-Jing; Guo Zongxia; Tian Wei Quan; Lei Shengbin

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Synthesis of One-Dimensional Schiff Base Polymers that Contain an Oligothiophene Building Block on the Graphite Surface

机译：在一维石墨表面上包含寡聚噻吩结构单元的一维席夫碱聚合物的合成

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Surface-mediated Schiff base coupling reactions between oligothiophenes equipped with an aldehyde group and aromatic diamines were investigated on highly oriented pyrolytic graphite (HOPG) by means of scanning tunneling microscopy (STM) under ambient conditions. To investigate the evolution process from monomers to resultant polymers and the mechanism of reactions, we controlled the ratio of precursors and the reactive temperature, and we obtained high-resolution STM images of different stages of the surface reaction. The results suggest that preferential adsorption of one kind of monomer has a great influence on the onsurface Schiff base reaction.

机译：在环境条件下，通过扫描隧道显微镜（STM），在高度取向的热解石墨（HOPG）上研究了具有醛基的低聚噻吩与芳族二胺之间的表面介导的席夫碱偶联反应。为了研究从单体到最终聚合物的演化过程以及反应机理，我们控制了前体的比例和反应温度，并获得了表面反应不同阶段的高分辨率STM图像。结果表明，一种单体的优先吸附对表面席夫碱反应有很大的影响。

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《Chemistry: A European journal》 |2015年第18期|共8页
作者
Sun Xiu-Ling; Fan Li-Xia; Yang Yong-Jing; Guo Zongxia; Tian Wei Quan; Lei Shengbin;
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正文语种 eng
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adsorption; oligothiophenes; polymers; scanning probe microscopy; Schiff bases;

机译：吸附;低聚噻吩;聚合物;扫描探针显微镜;席夫碱;

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1. Synthesis of One-Dimensional Schiff Base Polymers that Contain an Oligothiophene Building Block on the Graphite Surface [J] . Sun Xiu-Ling, Fan Li-Xia, Yang Yong-Jing, Chemistry: A European journal . 2015,第18期

机译：在一维石墨表面上包含寡聚噻吩结构单元的一维席夫碱聚合物的合成
2. meta-Phenylene-bridged double Schiff base copper(II) complexes as building blocks for 1D coordination polymers: Synthesis, crystal structure and magnetic properties [J] . Plaul D, Buchholz A, Gols H, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第15期

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4. Benzothiadiazole-cored regioregular oligothiophenes as building blocks for novel crystalline low band-gap conjugated polymers with solution processibility [C] . Lu Jianping, Liang Fushun, Drolet Nicolas, IEEE International Conference on Sustainable Energy Technologies . 2008

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5. Synthesis, Characterization, Magnetic Properties, DFT Calculations, and Electrochemical Properties of Salen Schiff Base Square Planar, and Square Pyramidal Metal Complexes, as Building Block for Synthesis of New Materials [D] . Gutierrez Gutierrez, Keily Jose 2019

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Synthesis of One-Dimensional Schiff Base Polymers that Contain an Oligothiophene Building Block on the Graphite Surface

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