Synthesis of Aza-Rocaglates via ESIPT-Mediated (3++2) Photocycloaddition

Wang Wenyu; Cencic Regina; Whitesell Luke; Pelletier Jerry; Porco John A. Jr.

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Synthesis of Aza-Rocaglates via ESIPT-Mediated (3++2) Photocycloaddition

机译：通过ESIPT介导的（3 ++ 2）光环加成法合成Aza-Rocaglates

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Synthesis of aza-rocaglates, nitrogen-containing analogues of the rocaglate natural products, is reported. The route features ESIPT-mediated (3+2) photocycloaddition of 1-alkyl-2-aryl-3-hydroxyquinolinones with the dipolarophile methyl cinnamate. A continuous photoflow reactor was utilized for photocycloadditions. An array of compounds bearing the hexahydrocyclopenta[b]indole core structure was synthesized and evaluated in translation inhibition assays.

机译：据报道，氮杂-rocaglates的合成是rocaglate天然产物的含氮类似物。该路线的特点是ESIPT介导的1-烷基-2-芳基-3-羟基喹啉酮与双极性亲子肉桂酸甲酯的（3 + 2）光环加成反应。连续光流反应器用于光环加成。合成了一系列带有六氢环戊[b]吲哚核心结构的化合物，并在翻译抑制试验中进行了评估。

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《Chemistry: A European journal》 |2016年第34期|共5页
作者
Wang Wenyu; Cencic Regina; Whitesell Luke; Pelletier Jerry; Porco John A. Jr.;
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正文语种 eng
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ESIPT; flow chemistry; heterocycles; photocycloaddition; rocaglate;

机译：ESIPT;流化学;杂环;光环加成;草酸盐;

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1. Synthesis of Aza-Rocaglates via ESIPT-Mediated (3++2) Photocycloaddition [J] . Wang Wenyu, Cencic Regina, Whitesell Luke, Chemistry: A European journal . 2016,第34期

机译：通过ESIPT介导的（3 ++ 2）光环加成法合成Aza-Rocaglates
2. Synthesis of Triazolodiazepinium Salts: Sequential [3++2] Cycloaddition/Rearrangement Reaction of 1-Aza-2-azoniaallenium Cation Intermediates Generated from Piperidin-4-ones [J] . Lin-bo Luan, Zi-jie Song, Zhi-ming Li, The Journal of Organic Chemistry . 2018,第7期

机译：三唑二氮杂氮盐的合成：顺序[3 + +2]环加成/重排反应从哌啶-4-哌啶-4-亚氮酰胺阳离子中间体的1-Aza-2-唑烯鎓阳离子中间体
3. SYNTHESIS AND INTRAMOLECULAR PHOTOCYCLOADDITIONS OF 2-ACYLOXY-3-HEXENOYL CYCLOHEXENONES - DIASTEREOSELECTIVITY IN THE INTRAMOLECULAR [2+2] PHOTOCYCLOADDITIONS OF ALKENES AND CYCLOHEXENONES TETHERED BY FOUR ATOMS [J] . Crimmins MT., Watson PS., Guise LE., Tetrahedron . 1997,第26期

机译：2-原子-3-环己烯基环己烯酮的合成和分子内光环化-通过四个原子合成的烯烃和环己烯基的分子内[2 + 2]光环化中的非对映选择性
4. Study on Synthesis of Amphiphilic Two-Dimensional Polymer by Photocycloaddition at Air/Water Interface [C] . Kohei Iritani, Yuki Uno, Kazuki Kunimoto 日本化学会春季年会講演予稿集 . 2018

机译：空气/水界面光电载入合成两亲二维聚合物的研究
5. 1. Application of the intramolecular crossed [2 + 2] photocycloaddition/retro-Mannich/Mannich cascade of vinylogous imides toward the synthesis of a sarain A bicycle. 2. Studies directed toward the synthesis of nakadomarin A [D] . Fitzgerald, Mark E. 2008

机译：1.分子内交叉的[2 + 2]光环加成反应/乙烯基乙烯基酰亚胺的复古-曼尼希/曼尼希级联在萨兰A自行车合成中的应用。 2.研究nakadomarin A的合成
6. Synthesis of Aza-Rocaglates via ESIPT-Mediated (3+2) Photocycloaddition [O] . Wenyu Wang, Dr. Regina Cencic, Dr. L. Luke Whitesell, -1

机译：通过ESIPT介导的（3 + 2）光环加成反应合成Aza-Rocaglates
7. Synthesis of cyclobutane fused γ-butyro lactones through intramolecular [2+2] photocycloaddition. Application in a formal synthesis of grandisol [O] . Jagannath Panda, Sarita Ghosh, Subrata Ghosh 2001

机译：通过分子内[2 + 2]光环加成合成环丁烷稠合γ-丁内酯。申请正式合成grandisol

Synthesis of Aza-Rocaglates via ESIPT-Mediated (3++2) Photocycloaddition

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