Recent Progress in Dehydro(genative) Diels-Alder Reaction

Li Wenbo; Zhou Liejin; Zhang Junliang

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Recent Progress in Dehydro(genative) Diels-Alder Reaction

机译：脱氢（代）Diels-Alder反应的最新进展

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In recent years, remarkable progress has been made in dehydro or dehydrogenative Diels-Alder (D-A) reactions. This Minireview gives an overview of the major two strategies for dehydro(genative) Diels-Alder reactions, which differ in dehydrogenation and D-A cyclization sequence. Reactions in which D-A cycloaddition is followed by dehydrogenation are useful methods for the synthesis of various aromatic compounds, whereas advancements in dehydro genative procedures with oxidants or catalysts prior to D-A cycloaddition offer yet further new routes to functionalized cycloadducts. Recent leading findings are highlighted and the current state of the art, scope, and limitations of these processes are discussed in this Minireview.

机译：近年来，在脱氢或脱氢Diels-Alder（D-A）反应中取得了显着进展。这篇小型综述概述了脱氢（生成性）Diels-Alder反应的两种主要策略，它们在脱氢和D-A环化顺序方面有所不同。在D-A环加成反应后进行脱氢反应是合成各种芳族化合物的有用方法，而在D-A环加成反应前用氧化剂或催化剂进行脱氢步骤的进展为官能化的环加合物提供了新的途径。在此Minireview中，重点介绍了最新的主要发现，并讨论了这些过程的最新技术，范围和局限性。

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《Chemistry: A European journal》 |2016年第5期|共14页
作者
Li Wenbo; Zhou Liejin; Zhang Junliang;
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正文语种 eng
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关键词
alkenes; alkynes; C-H activation; cycloaddition; photochemistry;

机译：烯烃;炔烃;C-H活化;环加成;光化学;

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1. Recent Progress in Dehydro(genative) Diels-Alder Reaction [J] . Li Wenbo, Zhou Liejin, Zhang Junliang Chemistry: A European journal . 2016,第5期

机译：脱氢（代）Diels-Alder反应的最新进展
2. Density functional study on intramolecular dehydro Diels-Alder reactions of conjugated enynes [J] . Lu YX, Yu QS, Zou HW Journal of Molecular Structure. Theochem: Applications of Theoretical Chemistry to Organic, Inorganic and Biological Problems . 2005,第1a3期

机译：共轭烯炔的分子内脱氢狄尔斯-阿尔德反应的密度泛函研究
3. Synthesis of carbazoles from ynamides by intramolecular dehydro Diels-Alder reactions [J] . Martinez-Esperon MF, Rodriguez D, Castedo L, Organic letters . 2005,第11期

机译：分子内脱氢狄尔斯-阿尔德反应从酰胺中合成咔唑
4. INFLUENCE OF THE C2 SUBSTITUENTS IN HOMOGENEOUS AND SUPPORTED Ti-TADDOLates ON THE STEREOSELECTIVITY IN DIELS-ALDER REACTIONS [C] . Belén Altava IUPAC international conference on polymer based technology . 2000

机译：均相和支撑的Ti-TADDOLATE中的C2取代基对Diels-Ader反应中立体选择性的影响
5. The synthesis of the A/B ring system of the arisugacins and territrems and studies on the intramolecular Diels-Alder reactions of furans and progress toward the total synthesis of the arisugacins and territrems . [D] . Min, Sun-Joon. 2005

机译：Arisugacins和Territrems的A / B环体系的合成及其呋喃分子内Diels-Alder反应的研究以及Arisugacins和Territrems的合成。
6. A Direct Route to 66’-Disubstituted-22’-Bipyridines by Double Diels-Alder/retro Diels-Alder Reaction of 55’-bi-124-Triazines [O] . Danuta Branowska 2005

机译：55-bi-124-三嗪的双Diels-Alder /复古Diels-Alder反应直接生成66-Di取代的22-联吡啶
7. Intramolecular Dehydro Diels-Alder Reactions of Diarylacetylenes: Switching between Benzob- and Benzocfluorenones as Products by Controlling the Rearrangement of Cyclic Allene Intermediates [O] . -1

机译：二芳基乙烯基的分子内脱氢Diels - alder反应：通过控制重新排列环苯甲烷中间体的苯并b - 和苯并c芴酮作为产品的切换

Recent Progress in Dehydro(genative) Diels-Alder Reaction

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