Phenanthro[4,5-fgh]quinoxaline-Fused Subphthalocyanines: Synthesis, Structure, and Spectroscopic Characterization

Pan Houhe; Liu Wenbo; Wang Chiming; Wang Kang; Jiang Jianzhuang

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Phenanthro[4,5-fgh]quinoxaline-Fused Subphthalocyanines: Synthesis, Structure, and Spectroscopic Characterization

机译：苯并[4,5-fgh]喹喔啉融合的亚酞菁类化合物：合成，结构和光谱表征

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A series of four phenanthro[4,5-fgh]quinoxaline-fused subphthalocyanine derivatives 0-3 containing zero, one, two, and three phenanthro[4,5-fgh] quinoxaline moieties, respectively, were isolated from the mixed cyclotrimerization reaction of 2,9-di-tert-butylphenanthro[4,5-fgh]quinoxaline-5,6-dicarbonitrile with 4,5-bis(2,6-diisopropylphenoxy)phthalonitrile and characterized by a series of spectroscopic methods including MALDI-TOF mass, H-1 NMR, electronic absorption, magnetic circular dichroism (MCD), and fluorescence spectroscopy. The molecular structures for the compounds 0 and 2 were clearly revealed on the basis of single-crystal X-ray diffraction analysis. Their electrochemical properties were also studied by cyclic voltammetry. In particular, theoretical calculations in combination with the electronic absorption and electrochemical analyses revealed the significant influence of the fused-phenanthro[4,5-fgh]quinoxaline units on the electronic structures.

机译：从的混合环三聚反应中分离出一系列分别含有零，一，二和三个菲并[4,5-fgh]喹喔啉部分的四个菲并[4,5-fgh]喹喔啉稠合的亚酞菁衍生物0-3。 2,9-二叔丁基菲咯[4,5-fgh]喹喔啉-5,6-二腈与4,5-双（2,6-二异丙基苯氧基）邻苯二甲腈，并通过包括MALDI-TOF质量在内的一系列光谱方法进行了表征，H-1 NMR，电子吸收，磁圆二色性（MCD）和荧光光谱。根据单晶X射线衍射分析，清楚地揭示出化合物0和2的分子结构。还通过循环伏安法研究了它们的电化学性质。特别是，理论计算与电子吸收和电化学分析相结合，揭示了对菲并[4,5-fgh]喹喔啉单元对电子结构的重大影响。

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来源
《Chemistry: A European journal》 |2016年第28期|共5页
作者
Pan Houhe; Liu Wenbo; Wang Chiming; Wang Kang; Jiang Jianzhuang;
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正文语种 eng
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electrochemistry; single-crystal structures; subphthalocyanine analogues; synthesis;

机译：电化学;单晶结构;亚酞菁类似物;合成;

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1. Phenanthro[4,5-fgh]quinoxaline-Fused Subphthalocyanines: Synthesis, Structure, and Spectroscopic Characterization [J] . Pan Houhe, Liu Wenbo, Wang Chiming, Chemistry: A European journal . 2016,第28期

机译：苯并[4,5-fgh]喹喔啉融合的亚酞菁类化合物：合成，结构和光谱表征
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Phenanthro[4,5-fgh]quinoxaline-Fused Subphthalocyanines: Synthesis, Structure, and Spectroscopic Characterization

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